366801-77-6Relevant academic research and scientific papers
Highly stereoselective 1,4-conjugate addition of organocopper reagents to methyl α-D-glucopyranoside derivatives tethering an unsaturated ester moiety at C-4 or C-6
Totani, Kiichiro,Nagatsuka, Takayuki,Takao, Ken-Ichi,Ohba, Shigeru,Tadano, Kin-Ichi
, p. 1447 - 1450 (1999)
(formula presented) The 1,4-conjugate additions of a variety of organocopper reagents to some 4-O-crotonyl derivatives of methyl α-D-glucopyranoside proceeded with a high level of diastereochemical induction to provide the adducts carrying a β-substituted
Highly diastereoselective 1,4-addition of an organocuprate to methyl α-D-gluco-, α-D-manno-, or α-D-galactopyranosides tethering an α,β-unsaturated ester. Novel asymmetric access to β-C-substituted butanoic acids
Totani,Nagatsuka,Yamaguchi,Takao,Ohba,Tadano
, p. 5965 - 5975 (2007/10/03)
The 1,4-addition of magnesium divinylcuprate prepared from vinylmagnesium bromide and cuprous bromide to some 4-O-crotonyl derivatives of methyl α-D-glucopyranoside proceeds with a high level of diastereochemical induction, providing the adduct in good-to
