367281-62-7

Upstream product

• 367281-61-6 N-allyl-2,6-diisopropylaniline 
• 24544-04-5 2,6-diisopropylbenzenamine 

Downstream Products

• 367281-63-8 2,6-diacetylpyridine bis(4-allyl-2,6-diisopropylaniline) 
• 412942-03-1 2-[1-(2,6-diisopropylphenylimino)ethyl]-6-[1-(4-allyl-2,6-diisopropylphenylimino)ethylpyridine] 
• 1293286-97-1 N,N′-bis-(4-allyl-2,6-diisopropylphenyl)ethanediimine 
• 1293286-96-0 1,3-bis-(4-allyl-2,6-diisopropylphenyl)imidazolium chloride 
• 564488-94-4 bis(4-allyl-2,6-diisopropylphenylimino)acenaphthene 

Relevant academic research and scientific papers

Highly stereoselective anti-Markovnikov hydrothiolation of alkynes and electron-deficient alkenes by a supported Cu-NHC complex

A practical, efficient, and low-cost heterogeneous catalyst consisting of a Cu-NHC (N-heterocyclic carbene) complex grafted to SBA-15 silica for the catalytic hydrothiolation of alkynes and electron-deficient alkenes under mild reaction conditions has been developed. The heterogeneous catalyst displays higher activity and stereoselectivity to Z-anti-Markovnikov isomers compared with the homogeneous analog under otherwise identical reaction conditions. The catalytic system is applicable to a broad range of alkynes and thiols and is recyclable without significant loss in catalytic performance. High activity and perfect selectivity to alkyl sulfides formed by the addition of electron-deficient alkenes to various thiols catalyzed by the supported Cu-NHC complex were also realized. This journal is the Partner Organisations 2014.

Polymerization catalyst composition

Copolymerization of Ni(II) or Co(II) acenaphthene imine complexes containing olefinic substituents on aryl groups with styrene in the presence of a radical initiator results in polymerized late transition metal catalysts which can be used for olefin polym

Ethylene polymerization by self-immobilized neutral nickel catalysts bearing allyl groups

[Ni(Ph)(PPh3)(N,O)] complexes containing phenyliminophenolato ligands (N,O) (1: N,O = A; 2: N,O = B; 3: N,O = C; 4: N,O = D; 5: N,O = E) have been synthesized and characterized. The molecular structure of 4 was determined by singlecrystal X-ray analysis. Complexes 2-5 bearing allyl groups have been investigated as self-immobilized catalysts for ethylene polymerization without the use of co-catalysts. The high ethylene polymerization activities of ca. 105 g·PE mol-1 Ni·h-1 and high molecular weight (MW ≈ 105) of polyethylene could be accomplished by changing the ligand structures and reaction conditions. The self-immobilization of catalysts brings about a dramatic increase in the catalytic activities of ethylene polymerization. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.