36749-63-0Relevant academic research and scientific papers
Oxygen-implanted MoS2 nanosheets promoting quinoline synthesis from nitroarenes and aliphatic alcohols via an integrated oxidation transfer hydrogenation-cyclization mechanism
Gao, Zhuyan,Huang, Zhipeng,Lu, Jianmin,Mu, Junju,Ren, Puning,Su, Kaiyi,Wang, Feng,Zhang, Chaofeng,Zhang, Shichao
, p. 1704 - 1713 (2022/03/08)
We herein report that MoS2 with oxygen-implanting modification (O-MoS2) can work as a multifunctional catalyst to achieve the one-pot quinoline synthesis from basic nitroarenes and aliphatic alcohols. Different from common knowledge that the application of MoS2-based catalysts and above quinoline synthesis need anaerobic conditions, we conduct the heterogeneous catalysis under an unusual air atmosphere. Catalyst characterization and experimental results indicate that the MoOx clusters implanted in the MoS2 skeleton, not the coordinatively unsaturated Mo sites (CUS Mo), dominate the generation of quinolines. By overturning the catalysis perception that O2 adsorption on MoSx can deactivate the MoS2-based catalysts using an efficient method for in situ healing of the MoOx structure in O-MoS2 and protecting the O-MoS2 catalyst by inhibiting unwanted MoOx elimination with extra H*, we innovatively introduce O2 into the quinoline synthesis. The robust O-MoS2 can be consecutively used ten times without regeneration and it offers 69-75% yields of 2-methylquinoline from nitrobenzene and ethanol. Furthermore, different from the traditional transfer hydrogenation-condensation mechanism, an integrated oxidation-transfer hydrogenation-cyclization mechanism is proposed over the O-MoS2 catalyst.
Simultaneous Generation of a [2 × 2] Grid-Like Complex and a Linear Double Helicate: a Three-Level Self-Sorting Process
Ayme, Jean-Fran?ois,Lehn, Jean-Marie,Bailly, Corinne,Karmazin, Lydia
supporting information, p. 5819 - 5824 (2020/03/30)
Two constitutional dynamic libraries (CDLs) - each containing two amines, two dialdehydes, and two metal salts - have been found to self-sort, generating two pairs of imine-based metallosupramolecular architectures (sharing no component) each with a [2 ×
Derivatives of 1,10- and 4,7-Phenanthrolinaldehydes and Di(N,N-di-ethylamino)ethoxyphenanthrolines as Potential Antitumor Agents
Mlochowski, Jacek,Palus, Jerzy
, p. 623 - 627 (2007/10/02)
The syntheses of 1,10- and 4,7-phenanthroline derivatives having glycidyl, oxaziridinyl, N,N-diethylaminoethoxy and thiosemicarbazone groups, and related compounds are reported.Their activities against experimental human tumor cells A 549 in vitro in relation to the molecular structures are discussed.
SYNTHESIS OF 5,6-DIAMINO-3,8-DIMETHYL-4,7-PHENANTHROLINE
Savosin, I. V.,Shaburov, V. V.
, p. 1550 - 1557 (2007/10/02)
Three gradually improving methods were developed for the synthesis of the previously undescribed 5,6-diamino-3,8-dimethyl-4,7-phenanthroline.The most promising is the direct amination of 5-nitro-3,8-dimethyl-4,7-phenanthroline.The IR spectra of 5-amino-3,
