3680-05-5Relevant academic research and scientific papers
Sulfinyl isobutyramide as an auxiliary for palladium(II)-catalyzed C-H arylation and iodination of benzylamine derivatives
Wang, Rui,Ding, Yongzheng,Li, Gang
supporting information, p. 4966 - 4970 (2017/07/10)
A novel readily available bidentate 2-methylsulfinyl isobutyramide directing group has been developed for benzylamine derivatives. It promoted ortho-C-H arylation and iodination of various substrates in good to excellent yields. The auxiliary is promising to be used in organic synthesis due to its versatility and convenient preparation from inexpensive materials.
Catalyse de l'oxydation par l'acid peracetique de sulfures organiques, contenant des fonctions fragiles, en sulfoxydes et sulfones correspondants
Rouchard, Jean,Moons, Chantal,Meyer, Joseph
, p. 441 - 443 (2007/10/02)
Organic sulfur compounds which contained supplementary susceptible functions (oxime, nitrile, acid, alcohol, oximecarbamate) were separately oxidised into the corresponding sulfoxides and sulfones with an anhydrous peracetic acid solution.Molybdenyl acetonylacetonate catalysed the oxidation toward the best conversions of the peracid, and the best selectivities for the sulfoxides and sulfones.
