36806-65-2

Basic information

• Product Name: (1R,4S,4aS,4bS,5R,8S,8aR,9aR)-4,4a,4b,5,8,8a,9,9a-octahydro-1H-1,4:5,8-dimethanofluorene
• CAS NO: 36806-65-2
• Molecular Formula: C₁₅H₁₈
• Molecular Weight: 198.3034
• Mol File: 36806-65-2.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 287.5°C at 760 mmHg
• Flash Point: 103.8°C
• Density: 1.121g/cm³
• Vapor Pressure: 0.00427mmHg at 25°C
• Refractive Index: 1.601
• CAS DataBase Reference: (1R,4S,4aS,4bS,5R,8S,8aR,9aR)-4,4a,4b,5,8,8a,9,9a-octahydro-1H-1,4:5,8-dimethanofluorene(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,4S,4aS,4bS,5R,8S,8aR,9aR)-4,4a,4b,5,8,8a,9,9a-octahydro-1H-1,4:5,8-dimethanofluorene(36806-65-2)
• EPA Substance Registry System: (1R,4S,4aS,4bS,5R,8S,8aR,9aR)-4,4a,4b,5,8,8a,9,9a-octahydro-1H-1,4:5,8-dimethanofluorene(36806-65-2)

Safety Data

• Hazardous Substances Data: 36806-65-2(Hazardous Substances Data)

Usage

General Description

The chemical "(1R,4S,4aS,4bS,5R,8S,8aR,9aR)-4,4a,4b,5,8,8a,9,9a-octahydro-1H-1,4:5,8-dimethanofluorene" is a complex, multi-ringed hydrocarbon compound. It consists of eight carbon atoms arranged in a fused, polycyclic structure, resulting in a stable, saturated ring system. This chemical has a unique and intricate spatial arrangement of atoms, giving it potential applications in organic chemistry, pharmacology, and materials science. Its specific properties and reactivity depend on the exact shape and structural arrangement of the molecule, making it an interesting subject for further study and potential use in various fields.

Upstream product

• 201230-82-2 carbon monoxide 
• 77-73-6 bi(cyclopentadiene) 
• 542-92-7 cyclopenta-1,3-diene 
• 534-22-5 2-methylfuran 
• 1755-01-7 endo-Dicyclopentadien 
• 933-60-8 exo-dicyclopentadiene 

Relevant articles and documents

Synthesis of high-density liquid fuel via Diels-Alder reaction of dicyclopentadiene and lignocellulose-derived 2-methylfuran

A process via Diels-Alder reaction of lignocellulose-derived 2-methylfuran and petroleum-derived dicyclopentadiene following by hydrodeoxygenation was proposed to synthesize a new kind high-density liquid fuel. The results show that the catalysts, temperature and reactant ratio can affect the product distribution of Diels-Alder reaction greatly. Among the investigated catalysts, HY zeolite exhibited the best catalytic activity and showed good recycling ability. Over HY zeolite, high conversion of reactants along with acceptable selectivity of the target products was obtained, under the reaction temperature of 150 °C and 2-MF/DCPD ratio of 2:1. After hydrodeoxygenation, the as-obtained fuel has a density of 0.984 g/mL, much higher than that of widely used JP-10 fuel (0.94 g/mL), a low freezing point of ?58 °C and a volumetric neat heat of combustion of 41.96 MJ/L. Furthermore, a blended fuel with 25% JP-10 exhibits high density and excellent cryogenic properties, which is very promising to serve as high-density fuel for advanced propulsion application.

Process for preparing TCD-diamine

A process for preparing 3(4),8(9)-bis(aminomethyl)tricycle-[5.2.1.02,6]decane by hydroformylating dicyclopentadiene with subsequent reductive amination wherein the hydroformylation of dicyclopentadiene is carried out in two stages, and, in a first hydroformylation stage, the reaction is effected in a heterogeneous reaction system using an aqueous solution of transition metal compounds, containing water-soluble organic phosphorus (III) compounds in complex-bound form, of group VIII of the Periodic Table to give 8(9)-formyltricyclo[5.2.1.02,6]dec-3-ene, and, in a second hydroformylation stage, the thus obtained 8(9)-formyltricyclo[5.2.1.02,6]dec-3-ene is converted, in a homogeneous organic phase in the presence of transition metal compounds of group VIII of the Periodic Table of the Elements to 3(4),8(9)-bisformyltricyclo[5.2.1.02,6]decane