36832-62-9

Upstream product

• 2525-40-8 prop-2-ynylsulfonylbenzene 
• 108-98-5 thiophenol 
• 5651-88-7 phenyl propargyl sulfide 
• 75354-86-8 1,6-bisphenylthiohexa-2,4-diyne 

Downstream Products

• 128500-88-9 C₃₂H₃₀O₆S₄ 
• 128500-90-3 C₃₂H₃₀O₆S₄ 
• 128500-89-0 C₃₂H₃₀O₆S₄ 
• 1315569-12-0 1,6-bis(phenylsulfonyl)hexa-1E,5Z-dien-3-yne 
• 1315569-11-9 1,6-bis(phenylsulfonyl)hexa-1E,5E-dien-3-yne 
• 1315569-15-3 2,6-diazido-1-(phenylsulfonyl)hex-2-en-4-yne 
• 1315569-16-4 2-azido-1,6-bis(phenylsulfonyl)hex-2-en-4-yne 
• 1315569-13-1 (E,Z)-2,5-diaza-1,6-bis(phenylsulfonyl)hexa-2,4-diene 
• 1315569-17-5 1,6-bis(phenylsulfonyl)-2-(4,5,6,7,8,9-hexahydrocycloocta-1H-1,2,3-triazol-1-yl)hexa-2-en-4-yne 
• 1315569-19-7 2-(3-azidoprop-1-ynyl)-3-[(phenylsulfonyl)methyl]-2H-azirine 
• 1315569-18-6 3-[(phenylsulfonyl)methyl]-2-[3-(phenylsulfonyl)prop-1-ynyl]-2H-azirine 
• 132901-65-6 C₂₄H₂₂O₆S₃ 
• 132901-65-6 C₂₄H₂₂O₆S₃ 
• 134269-42-4 C₃₀H₂₆O₄S₄ 

Relevant academic research and scientific papers

Reduction of propargylic sulfones to (Z)-allylic sulfones using zinc and ammonium chloride

Propargylic sulfones can be cis-hydrogenated using commercial zinc powder and ammonium chloride in THF-water at room temperature, the major products being the corresponding (Z)-allylic sulfones. Other reducible groups (alkene, benzyloxy) are not affected. Allenylsulfones are implicated in one of the possible reaction pathways.

The Mass Spectral Rearrangements of 1,6-Bis(arylsulfenyl)-2,4-hexadiynes and 1,6-Bis(arylsulfonyl)-2,4-Hexadiynes

The mass spectral behavior of 1,6-bis(arylsulfenyl)-2,4-hexadiynes and 1,6-bis(arylsulfonyl)-2,4-hexadiynes were examined.The sulfenyl derivatives extruded the hexadiynyl moiety with the formation of Ar-S-S-Ar fragments.The sulfonyl derivatives, on the other hand, showed no extrusion of the hexadiyne fragment but an expulsion of SO2 and even two SO2 units.