368446-69-9Relevant academic research and scientific papers
π-facial diastereoselection of hydride reduction of 1,3-diheteran-5-ones: Application of the exterior frontier orbital extension model
Kaneno, Daisuke,Zhang, Jian,Iwaoka, Michio,Tomoda, Shuji
, p. 358 - 368 (2001)
To obtain further evidence for the importance of the ground state conformational and orbital properties in π-facial diastereoselection of 1,3-diheteran-5-ones (heteroatom = O, S, Se), 2-phenyl-1,3-diselenan-5-one (3a) has been synthesized, and its π-facia
