368873-85-2

Basic information

• Product Name: IMIDAZOL-1-YL-DIFLUOROMETHYL-DIPHENYLPHOSPHINE
• Synonyms: IMIDAZOL-1-YL-DIFLUOROMETHYL-DIPHENYLPHOSPHINE;1H-Imidazole, 1-[(diphenylphosphino)difluoromethyl]-
• CAS NO: 368873-85-2
• Molecular Formula: C16H13F2N2P
• Molecular Weight: 302.263
• Mol File: 368873-85-2.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 398.1°C at 760 mmHg
• Flash Point: 194.6°C
• Appearance: /
• Vapor Pressure: 3.47E-06mmHg at 25°C
• CAS DataBase Reference: IMIDAZOL-1-YL-DIFLUOROMETHYL-DIPHENYLPHOSPHINE(CAS DataBase Reference)
• NIST Chemistry Reference: IMIDAZOL-1-YL-DIFLUOROMETHYL-DIPHENYLPHOSPHINE(368873-85-2)
• EPA Substance Registry System: IMIDAZOL-1-YL-DIFLUOROMETHYL-DIPHENYLPHOSPHINE(368873-85-2)

Safety Data

• Hazardous Substances Data: 368873-85-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C16H13F2N2P/c17-16(18,20-12-11-19-13-20)21(14-7-3-1-4-8-14)15-9-5-2-6-10-15/h1-13H

Upstream product

• 1079-66-9 chloro-diphenylphosphine 
• 328406-16-2 1-bromodifluoromethylimidazole 

Relevant articles and documents

Generation of heteroarylium-N-difluoromethylides and heteroaryl-N-difluoromethyl anions and their reactions with electrophiles: Heteroaryl- and heteroarylium-N-difluoromethyl trimethylsilanes and a new heteroaryl-N-trifluoromethane

Reductive debromination of N-bromodifluoromethyl-4-dimethylaminopyridinium bromide, 1-bromodifluoromethyl-imidazole, 1-methyl-3-bromodifluoromethyl-imidazolium bromide and 1-bromodifluoromethyl-2-methyl-benzimidazole using tetrakis(dimethylamino)ethylene (TDAE) or tris(diethylamido)phosphite leads to new fluorinated carbanionic species, namely heteroarylium-N-difluoromethylides and heteroaryl-N-difluoromethyl anions. In the presence of electrophiles such as benzaldehyde, chlorodiphenylphosphine and chlorotrimethylsilane, the corresponding heteroarylium- and heteroaryl-N-difluoromethylated derivatives, imidazole-N-difluoromethyl-phosphines and -silanes, 2-methyl-benzimidazole-N-difluoromethyltrimethyl-carbinols-phosphines and -silanes were obtained. Similar 4-dimethylaminopyridinium derivatives were synthesized.