369-52-8Relevant academic research and scientific papers
Arylseleninic acid as a green, bench-stable selenylating agent: Synthesis of selanylanilines and 3-selanylindoles
Abenante, Laura,Anghinoni, Jo?o M.,Lenard?o, Eder J.,Padilha, Nathalia B.,Penteado, Filipe,Rosati, Ornelio,Santi, Claudio,Silva, Marcio S.
supporting information, p. 5210 - 5217 (2020/07/23)
Arylseleninic acids were used as an electrophilic selenium source in aromatic substitution reactions, using N,N-substituted anilines and indoles as nucleophiles at 70 °C for 6-15 h. A total of fourteen 4-selanylanilines and five 3-selanylindoles were selectively obtained in good to excellent yields. The starting benzeneseleninic acids are easily prepared from the respective diselenides, are bench stable and easy to handle, affording water as the only waste at the end of the reaction. This journal is
THE OXIDATION OF ARYL DISELENIDES WITH AN EQUIMOLAR AMOUNT OF tert-BUTYL HYDROPEROXIDE: EVIDENCE AGAINST THE FORMATION OF SIGNIFICANT AMOUNTS OF A SELENENIC ANHYDRIDE
Gancarz, Roman A.,Kice, John L.
, p. 1661 - 1662 (2007/10/02)
Reaction of equimolar quantites of an aryl diselenide (1) and tert-butyl hydroperoxide does not lead, as has been suggested, to a substantial amount of the corresponding selenenic anhydride (4), but rather to a mixture of seleninic anhydride (2) and unreacted diselenide, in a mole ratio of 1:2.
