3695-88-3Relevant academic research and scientific papers
Isomerisation of benzopyran-2-imines in [2H6]dimethyl sulfoxide
O'Callaghan, Conor N.,McMurry, T. Brian H.,O'Brien, John E.
, p. 425 - 429 (2007/10/03)
When 2-imino-2H-benzopyran-3-carboxamide 1 (X = H) is dissolved in [2H6]dimethyl sulfoxide, NMR spectra show that a mixture of 1 and the isomeric 2-cyano-3-(2-hydroxyphenyl)prop-2-ene-1-carboxamide 3 (X = H) is present. Other benzopyran-2-imines behave similarly; the degree of isomerisation varies considerably, depending on the nature and position of the substituents present.
