370069-67-3

Basic information

• Product Name: 1,2,3-tris(bromomethyl)benzene
• Synonyms: 1,2,3-tris(bromomethyl)benzene
• CAS NO: 370069-67-3
• Molecular Weight: 356.882
• Mol File: 370069-67-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,2,3-tris(bromomethyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,3-tris(bromomethyl)benzene(370069-67-3)
• EPA Substance Registry System: 1,2,3-tris(bromomethyl)benzene(370069-67-3)

Safety Data

• Hazardous Substances Data: 370069-67-3(Hazardous Substances Data)

Upstream product

• 13651-14-4 (2,3-dimethylphenyl)methanol 
• 526-73-8 1,2,3-trimethylbenzene 

Downstream Products

• 370069-71-9 1,2,3-tris(1,4,7-triazacyclonon-1-ylmethyl)benzene 

Relevant articles and documents

Structural, spectroscopic and electrochemical studies of nickel(II) "sandwich" complexes with ligands featuring tethered 1,4,7-triazacyclononane macrocycles

A structural and electrochemical study of the nickel(II) complexes, [Ni(tacn)2](ClO4)2 (1), [NiLeth](ClO4)2 (2), [NiLox](ClO4)2·H2O (3), [Ni

X-Ray structure determinations of bromo and/or bromomethylsubstituted benzenes: C-H···Br, C-Br···Br, and C-Br···p interactions

The structures of seven benzene derivatives [1,2,3-tri(bromomethyl)benzene, (1); 3,5-di(bromomethyl)bromobenzene, (2); 2,5-di(bromomethyl)bromobenzene, (3); 4-(bromomethyl)-2,5-dibromotoluene, (4); 4-(bromomethyl)bromobenzene, (5); 2,3-di(bromomethyl)bromobenzene, (6) and (bromomethyl)-p-dibromobenzene, (7)] with bromo and bromomethyl (and in one case methyl) substituents are presented and analysed in terms of Br···Br interactions up to 4.0 A , supported by hydrogen bonds H···Br. Some interactions of the type Br···π and π·· · π are encountered and play a subordinate role in the packing. Despite the close chemical similarity of the compounds, some of which are isomers with permuted substituent positions, the packing motifs are highly variable. Compounds 2-5 are based on layer structures with Brn (n=3, 4) and/or mixed Br/C rings. Compounds 1, 6 and 7 display three-dimensional packings of differing complexity, but with interpretable substructures; 1 can be analysed in terms of ribbons of linked Br3 and Br4 rings; 6 displays chains of linked Br3 triangles; 7 consists of ribbons of linked Br4 quadrilaterals.