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6-(4-(methylthio)phenyl)-1,2,3,5,6,10b-hexahydropyrrolo[2,1-a]isoquinoline is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

370102-67-3

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370102-67-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 370102-67-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,7,0,1,0 and 2 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 370102-67:
(8*3)+(7*7)+(6*0)+(5*1)+(4*0)+(3*2)+(2*6)+(1*7)=103
103 % 10 = 3
So 370102-67-3 is a valid CAS Registry Number.

370102-67-3Downstream Products

370102-67-3Relevant academic research and scientific papers

HIGHLY STEREOCONTROLLED PROTON TRANSFER IN AN ENAMMONIUM-IMINIUM REARRANGEMENT. MECHANISM OF THE STEREOSELECTIVE DEOXYGENATION OF 6-ARYL-6-HYDROXY-1,2,3,5,6,10b-HEXAHYDROPYRROLOISOQUINOLINES WITH BORANE-THF IN TRIFLUOROACETIC ACID.

Maryanoff, Bruce E.,McComsey, David F.,Mutter, Martin S.,Sorgi, Kirk L.,Maryanoff, Cynthia A.

, p. 5073 - 5076 (1988)

Either diastereomer of 2 or 10 is deoxygenated with BH3-THF/CF3CO2H to give mainly the trans product, 3b or 11b.The process involes a key enammonium-iminium rearrangement in which there is almost exclusive proton delivery from a single face.

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