37026-90-7Relevant academic research and scientific papers
The heterogeneous catalytic heck reaction in an ionic liquid
Aslanov,Valetskii,Volkov,Zakharov,Kabachii,Kochev,Romanovskii,Yatsenko
, p. 2238 - 2242 (2008)
The C-C cross coupling reaction between bromobenzene and styrene in the presence of Pd deposited on mesoporous acetylene soot (Pd/C) occurred in a tetraalkylammonium ionic liquid (IL) as a truly heterogeneous catalytic process. The active palladium form was not transferred into the reaction solution. Deposited palladium activation was observed when the Pd/C catalyst was preliminarily heated in the IL in the presence of dibutylamine as a base. Pleiades Publishing, Ltd., 2008.
Heterogeneous catalysis in ionic liquids: The heck reaction of bromobenzene with styrene over palladium supported on mesoporous carbon
Aslanov,Valetskii,Zakharov,Kabachii,Kochev,Romanovskii,Yatsenko
, p. 360 - 365 (2008)
Tributylhexylammonium bistriflamide [(C4H9)(C 6H13)N][(CF3SO2)2N], an ionic liquid, was used as a solvent for the Heck reaction of bromobenzene with styrene in the presence of Pd deposited onto a mesoporous carbon support. It was found that dibutylamine used as a basic reagent to scavenge hydrogen bromide results in higher conversions of the reactants and higher yields of stilbene than sodium acetate. It was shown that the IL is fully recoverable after use in the catalytic reaction.
Ionic liquids miscible with various polar/non-polar solvents and method of preparing the same
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Page/Page column 4, (2009/10/18)
Provided are an ionic liquid and a method of preparing the same. The ionic liquid includes at least one type of compound represented by (Cat+)(R′COO?). Here, the Cat+ is a cation selected from the group consisting of quate
