37051-55-1

Basic information

• Product Name: 3-Cyclohexene-1-carboxylic acid, 5-oxo-, methyl ester
• CAS NO: 37051-55-1
• Molecular Formula: C8H10O3
• Molecular Weight: 154.166
• Mol File: 37051-55-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 3-Cyclohexene-1-carboxylic acid, 5-oxo-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Cyclohexene-1-carboxylic acid, 5-oxo-, methyl ester(37051-55-1)
• EPA Substance Registry System: 3-Cyclohexene-1-carboxylic acid, 5-oxo-, methyl ester(37051-55-1)

Safety Data

• Hazardous Substances Data: 37051-55-1(Hazardous Substances Data)

Upstream product

• 41088-52-2 methyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate 
• 18448-47-0 methyl cyclohex-1-ene-1-carboxylate 
• 137033-09-1 3-(tert-Butyl-dimethyl-silanyloxy)-4-p-tolylsulfanyl-cyclohex-3-enecarboxylic acid methyl ester 
• 19914-92-2 (+/-)-4-iodo-6-oxabicyclo[3.2.1]octan-7-one 
• 54911-89-6 cis-methyl 5-hydroxycyclohex-3-enecarboxylate 
• 4771-80-6 1,2,5,6-tetrahydrobenzoic acid 
• 4720-83-6 6-oxabicyclo[3.2.1]oct-3-en-7-one 
• 1630-01-9 cis-3,4-Epoxycyclohexanecarboxylic acid methyl ester 
• 22748-45-4 5-oxocyclohex-3-ene-1-carboxylic acid 
• 74-88-4 methyl iodide 
• 137033-05-7 3-(p-tolylthio)-2-(trimethylsilyloxy)-1,3-butadiene 
• 292638-85-8 acrylic acid methyl ester 

Downstream Products

• 80256-16-2 methyl 3-dimethylphenylsilyl-4-methyl-5-oxocyclohexanecarboxylate 

Relevant articles and documents

Metal-Free I2-Catalyzed Highly Selective Dehydrogenative Coupling of Alcohols and Cyclohexenones

The I2 catalyzed highly selective oxidative condensation of cyclohexenones and alcohols for the synthesis of aryl alkyl ethers has been described. DMSO is employed as the mild terminal oxidant. This novel methodology offers a metal-free reaction condition, operational simplicity and broad substrate scope to afford valuable products from inexpensive reagents. Various meta-substituted aromatic ethers which are hardly synthesized from the reported methods requiring meta-substituted phenols, are efficiently prepared by the present protocol.

Reactions of 1-methoxycarbonyl-3-cyclohexene and 3,4-epoxy-1-methoxycarbonyl-cyclohexane with tert-butoxy radical

Reactions of 1-methoxycarbonyl-3-cyclohexene and 3,4-epoxy-1-methoxycarbonylcyclohexane (as a 63:37 mixture of trans and cis isomers or pure trans isomers) with tert-butoxy radical at 413 K yield oligomeric products. In the case of epoxy derivatives, 1-methoxycarbonyl-4-cyclohexen-3-ol, 1-methoxycarbonyl-4-cyclohexen-3-one, and 1-methoxycarbonyl-3-cyclohexanone are also formed. This set of products indicates that tert-butoxy radical abstracts a hydrogen atom from the 2-position of the cyclohexene ring and from the 2,3- or 4,5-positions of the cyclohexane ring. 1996 MAEe Cyrillic signΚ Hayκa/Interperiodica Publishing.

Simple Synthesis and the Diels-Alder Reaction of 3-(p-Tolylthio)-2-(trimethylsilyloxy)-1,3-butadiene

The reaction of 3-(p-tolylsulfinyl)-2-butanone with trimethylsilyl trifluoromethanesulfonate in the presence of diisopropylethylamine gave 3-(p-tolylthio)-2-(trimethylsilyloxy)-1,3-butadiene (2) quantitatively.The Diels-Alder reactions of 2 and the relate