370861-83-9Relevant academic research and scientific papers
Gold-catalysed synthesis of exocyclic vinylogous amides and β-amino ketones: A detailed study on the 5-exo/6-endo-dig selectivity, methodology and scope
Scarpi, Dina,Begliomini, Stefano,Prandi, Cristina,Oppedisano, Alberto,Deagostino, Annamaria,G?mez-Bengoa, Enrique,Fiser, Béla,Occhiato, Ernesto G.
, p. 3251 - 3265 (2015/05/20)
The gold(I)-catalysed reaction of N-Boc-protected 6-alkynyl-3,4-dihydro-2H-pyridines, which gives synthetically useful vinylogous amides (β-enaminones), has been studied in detail, in order to optimize the reaction conditions, enlarge the scope and gain i
P-C cross-coupling onto enamides: Versatile synthesis of α-enamido phosphane derivatives
Cieslikiewicz, Monika,Bouet, Alexis,Juge, Sylvain,Toffano, Martial,Bayardon, Jerome,West, Caroline,Lewinski, Krzystof,Gillaizeau, Isabelle
supporting information; experimental part, p. 1101 - 1106 (2012/04/10)
We report herein the Pd-catalyzed P-C cross-coupling reaction between enol phosphates and secondary phosphane-borane complexes or phosphane oxides. The reaction was performed under mild conditions, owing to Pd activation of the P-H bonds of the phosphane-
Palladium-catalyzed coupling of vinyl phosphates with aryl or heteroaryl boronic acids. Application to the synthesis of substituted nitrogen containing heterocycles
Lepifre, Franck,Clavier, Sylvain,Bouyssou, Pascal,Coudert, Gérard
, p. 6969 - 6975 (2007/10/03)
Substituted nitrogen-containing heterocycles were prepared in three steps from commercially available derivatives via an extension of the Suzuki reaction involving the palladium-catalyzed coupling of vinyl phosphates with aryl or heteroaryl boronic acids.
Synthesis of N-heterocycles via lactam-derived ketene aminal phosphates. Asymmetric synthesis of cyclic amino acids
Nicolaou,Shi, Guo-Qiang,Namoto, Kenji,Bernal, Federico
, p. 1757 - 1758 (2007/10/03)
A variety of N-heterocycles can be synthesized from lactams via Pd0-catalyzed couplings of their corresponding enol phosphates.
