370886-66-1

Basic information

• Product Name: (2R,3S,5R,6S)-2-[(4-Methoxy-phenyl)-diphenyl-methoxymethyl]-5-triisopropylsilanyloxy-6-vinyl-tetrahydro-pyran-3-ol
• Synonyms: (2R,3S,5R,6S)-2-[(4-Methoxy-phenyl)-diphenyl-methoxymethyl]-5-triisopropylsilanyloxy-6-vinyl-tetrahydro-pyran-3-ol
• CAS NO: 370886-66-1
• Molecular Weight: 602.886
• Mol File: 370886-66-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,3S,5R,6S)-2-[(4-Methoxy-phenyl)-diphenyl-methoxymethyl]-5-triisopropylsilanyloxy-6-vinyl-tetrahydro-pyran-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3S,5R,6S)-2-[(4-Methoxy-phenyl)-diphenyl-methoxymethyl]-5-triisopropylsilanyloxy-6-vinyl-tetrahydro-pyran-3-ol(370886-66-1)
• EPA Substance Registry System: (2R,3S,5R,6S)-2-[(4-Methoxy-phenyl)-diphenyl-methoxymethyl]-5-triisopropylsilanyloxy-6-vinyl-tetrahydro-pyran-3-ol(370886-66-1)

Safety Data

• Hazardous Substances Data: 370886-66-1(Hazardous Substances Data)

Upstream product

• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 
• 14470-28-1 mono-4-methoxytrityl chloride 
• 370886-82-1 (2R,3S,5R,6S)-2-Hydroxymethyl-5-triisopropylsilanyloxy-6-vinyl-tetrahydro-pyran-3-ol 

Downstream Products

• 1053655-14-3 (2R,4R,4aS,6R,7R,8aR)-7-Benzyloxy-2-{3-[(2R,3R,4S)-4-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-prop-1-ynyl}-6-benzyloxymethyl-4-(4-methoxy-benzyloxy)-octahydro-pyrano[3,2-b]pyran-2-ol 
• 370886-87-6 ((2R,3R,4S)-4-Benzyloxy-2-{3-[(2R,4R,4aS,6R,7R,8aR)-7-benzyloxy-6-benzyloxymethyl-4-(4-methoxy-benzyloxy)-octahydro-pyrano[3,2-b]pyran-2-yl]-prop-2-ynyl}-tetrahydro-pyran-3-yloxy)-tert-butyl-dimethyl-silane 
• 675834-58-9 1-((2R,4S,4aR,6R,7R,8aR)-7-Benzyloxy-6-benzyloxymethyl-4-chloro-octahydro-pyrano[3,2-b]pyran-2-yl)-3-[(2R,3S,4S)-4-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-propane-1,2-diol 
• 1055029-63-4 1-((2R,4S,4aR,6R,7R,8aR)-7-Benzyloxy-6-benzyloxymethyl-4-chloro-octahydro-pyrano[3,2-b]pyran-2-yl)-3-[(2R,3S,4S)-4-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-propane-1,2-dione 
• 1055028-95-9 (2R,4R,4aS,6R,7R,8aR)-7-Benzyloxy-2-{(Z)-3-[(2R,3R,4S)-4-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2-yl]-propenyl}-6-benzyloxymethyl-octahydro-pyrano[3,2-b]pyran-4-ol 
• 370886-89-8 {(2R,3R,4S)-4-Benzyloxy-2-[(Z)-3-((2R,4S,4aR,6R,7R,8aR)-7-benzyloxy-6-benzyloxymethyl-4-chloro-octahydro-pyrano[3,2-b]pyran-2-yl)-allyl]-tetrahydro-pyran-3-yloxy}-tert-butyl-dimethyl-silane 
• 1054663-75-0 (2S,3S,4aR,8S,8aS,2'R,4'S,4'aR,6'R,7'R,8'aR)-8,7'-Bis-benzyloxy-6'-benzyloxymethyl-4'-chloro-dodecahydro-[2,2']bi[pyrano[3,2-b]pyranyl]-2,3-diol 
• 370886-91-2 (2R,4aR,8S,8aS,2'R,4'S,4'aR,6'R,7'R,8'aR)-8,7'-Bis-benzyloxy-6'-benzyloxymethyl-4'-chloro-2-hydroxy-dodecahydro-[2,2']bi[pyrano[3,2-b]pyranyl]-3-one 
• 370886-93-4 (2S,3S,4aR,8S,8aS,2'R,4'S,4'aR,6'R,7'R,8'aR)-8,7'-Bis-benzyloxy-6'-benzyloxymethyl-4'-chloro-hexadecahydro-[2,2']bi[pyrano[3,2-b]pyranyl]-3-ol 
• 370886-70-7 (R)-1-((2S,3R,5R,6R)-5-Benzyloxy-6-benzyloxymethyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-but-3-en-1-ol 
• 370886-80-9 (2R,3R,5R,6R)-5-Benzyloxy-6-benzyloxymethyl-2-[(R)-1-(4-methoxy-benzyloxy)-but-3-enyl]-tetrahydro-pyran-3-ol 
• 370886-74-1 (4R,4aS,6R,7R,8aR)-7-Benzyloxy-6-benzyloxymethyl-4-(4-methoxy-benzyloxy)-hexahydro-pyrano[3,2-b]pyran-2-one 
• 1054632-30-2 (R)-3-((2R,3R,5R,6R)-5-Benzyloxy-6-benzyloxymethyl-3-hydroxy-tetrahydro-pyran-2-yl)-3-(4-methoxy-benzyloxy)-propionaldehyde 
• 370886-85-4 (2R,3R,5R,6R)-5-Benzyloxy-6-benzyloxymethyl-3-triisopropylsilanyloxy-tetrahydro-pyran-2-carbaldehyde 

Relevant articles and documents

Synthesis and stereochemical confirmation of the HI/JK ring system of prymnesins, potent hemolytic and ichthyotoxic glycoside toxins isolated from the red tide alga

Stereocontrolled synthesis of the HI/JK ring model of the prymnesins, glyosidic toxins isolated from the red tide phytoflagellate Prymnesium parvum, is described. Comparison of its 1H and 13C NMR data with those of the natural toxins established the earlier stereochemical assignments.