37091-73-9 Usage
Description
2-Chloro-1,3-dimethylimidazolidinium chloride has various applications including being used as activating agent in total synthesis of macroviracin A, cycloviracin B1 and cyclic silanes; used as reagent for synthesis of tagged glucose as an intermediate in the synthesis of branched oligosaccharides; used as fluorescent chemosensors; 1,2-Diamines as inhibitors of co-activator associated arginine methyltransferase 1; used as allosteric glucokinase activators; as reactant for synthesis of organic azides from primary amines and for aza-Henry reactions1. It can act as a powerful dehydrating agent, replacing DCC under nearly neutral conditions, and has application for the construction of heterocycles2. Moreover, it can be used for one-pot synthesis of 2-aminobenzimidazoles3. It is also applicable to chlorination, oxidation, reduction, and rearrangement under nearly neutral conditions4.
Sources
https://www.sigmaaldrich.com/catalog/product/aldrich/529249?lang=en®ion=US
https://pubs.acs.org/doi/abs/10.1021/jo990210y
www.sciencedirect.com/science/article/pii/S004040391001395X
J. Org. Chem., 1999, 64 (16), pp 5832–5835
Chemical Properties
Brown Solid
Uses
Different sources of media describe the Uses of 37091-73-9 differently. You can refer to the following data:
1. Used in the one-pot synthesis of 2-aminobenzimidazoles.
2. Reagent for synthesis of: Tagged glucose as an intermediate in the synthesis of branched oligosaccharides Fluorescent chemosensors 1,2-Diamines as inhibitors of co-activator associated arginine methyltransferase 1 Allosteric glucokinase activatorsReactant for synthesis of: Organic azides from primary aminesReagent for aza-Henry reactions
Check Digit Verification of cas no
The CAS Registry Mumber 37091-73-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,7,0,9 and 1 respectively; the second part has 2 digits, 7 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 37091-73:
(7*3)+(6*7)+(5*0)+(4*9)+(3*1)+(2*7)+(1*3)=119
119 % 10 = 9
So 37091-73-9 is a valid CAS Registry Number.
InChI:InChI=1/C5H10ClN2.ClH/c1-7-3-4-8(2)5(7)6;/h3-4H2,1-2H3;1H/q+1;/p-1
37091-73-9Relevant articles and documents
UEBER STERISCH GEHINDERTE FREIE RADIKALE XI. DIE ERSTE REVERSIBLE THERMISCHE DISSOZIATION VON DISILANEN R3Si-SiR3 ZU SILYLRADIKALEN R3Si. UND VON DIGERMANEN R3Ge-GeR3 ZU GERMYLRADIKALEN R3Ge.
Neumann, Wilhelm P.,Schultz, Klaus-Dieter,Vieler, Robert
, p. 179 - 192 (2007/10/02)
The Si-Si bond in hexamesityldisilane dissociates reversibly even between -60 and -32 deg C (ΔHdiss 19.0 +/- 2 kcal mol-1) and the Ge-Ge bond in hexamesityldigermane reversibly between -12 and +53 deg C (ΔHdiss 20.7 +/- 2
