37096-99-4Relevant academic research and scientific papers
Catalytic application of two novel sandwich-type polyoxometalates in synthesis of 14-substituted-14H-dibenzo[a, j]xanthenes
Sheshmani, Shabnam
, p. 345 - 351 (2013)
Two sandwich-type polyoxometalates K12[As2W 18Cu3O68]·30H2O and K 12[As2W18U3O74] ·21H2O were found to be as novel efficien
Fabrication of activated carbon sulfuric acid as an excellent and novel solid acid catalyst, evaluating its catalytic activity in synthesizing 1,8-dioxo-octahydroxanthenes and 14-aryl-14H-dibenzo[a,j]xanthenes
Marandi, Alireza,Koukabi, Nadiya,Zolfigol, Mohammad Ali
, p. 3145 - 3163 (2021/05/03)
In this work, for the first time, a novel and innovative procedure has been utilized to chemically functionalize activated carbon (AC) based on the sulfonation reaction, which can be used in catalytic reactions as a strong solid acid. For this aim, AC mus
Solvent-free synthesis of 14-aryl-14H-dibenzo[a-j]xanthenes using Fe3O4@Al2O3@SiO2@Fe2O3 as a green catalyst
Darya, Naghmeh,Tajik, Hassan
supporting information, p. 3546 - 3564 (2021/11/04)
We report, a novel, green, nano-sized particles as a sandwich nano-capsule multilayer catalyst (SNC@MC) [Fe3O4@Al2O3@SiO2@Fe2O3] for the efficacious one-pot synthesis of 14-aryl-
Alkene-modified Fe3O4 nanoparticle-mediated construction of functionalized mesoporous poly(ionic liquid)s: Synergistic catalysis of mesoporous confinement effect and hydrogen proton for organic transformations
Liu, Zhong-Qiu,Li, Sheng-Nan,Zeng, Qing-Shuai,Liu, Yu-Jing,You, Jin-Mao,Ying, An-Guo
, (2021/02/21)
The preparation of mesoporous poly(ionic liquid)s (MPILs) is critically fundamental for the design of heterogeneous catalysts, whereas traditional methods are difficult to obtain these materials with both well-defined mesoporous structure and unique functionality. Here, HClO4-functionalized MPILs with well-defined mesoporous structure were successfully fabricated, in which the alkene-modified Fe3O4 nanoparticles as structural reinforcer play a vital role for mesoporous structure formation. The MPILs were characterized by N2 adsorption/desorption, scanning electron microscope (SEM), transmission Electron Microscope (TEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and vibration sample magnetometry (VSM), and the results confirm that MPILs possess moderate surface area, well-defined mesoporosity, abundant active ionic centers, as well as efficient magnetic recovery. The resulting MPILs show excellent catalytic activity for condensation reaction and Knoevenagel condensation. The kinetic study reveals that the excellent catalytic activity of MPILs is attributed to the synergistic catalysis of mesoporous confinement effect and hydrogen proton from MPILs, albeit with mass transfer resistance produced by mesoporous channels. Further, the catalyst can be recovered using an external magnetic field and reused at least 10 times without a considerable decrease in its catalytic activity. Finally, alkene-modified Fe3O4 nanoparticle-mediated mesoporous construction promotes a textural engineering approach to the development of novel mesoporous materials for other applications.
Br?nsted Acidic Ionic Liquid-Catalyzed Synthesis of 14-Aryl-14H-dibenzo[a,j]xanthenes with Controlled Microwave Heating under Solvent-Free Conditions
Huynh, C. C.,Le, T. N.,Tran, P. H.
, p. 504 - 508 (2020/04/29)
Abstract: 1-Methyl-3-sulfo-1H-imidazol-3-ium chloride([Msim]Cl) catalyzed the condensation of β-naphthol with aromatic aldehydesunder microwave irradiation. This method is efficient to synthesizedibenzoxanthene derivatives in excellent yields, and the cat
Nano-ZnO Impregnated on Starch—A Highly Efficient Heterogeneous Bio-Based Catalyst for One-Pot Synthesis of Pyranopyrimidinone and Xanthene Derivatives as Potential Antibacterial Agents
Amininia,Pourshamsian,Sadeghi
, p. 1279 - 1288 (2020/10/02)
Abstract: A new method has been proposed for the synthesis of pyranopyrimidinone andxanthene derivatives using zinc oxide–starch nanocomposite as catalyst undermicrowave irradiation. The ZnO–starch nanocomposite was characterized by X-raydiffraction and s
High acidity cellulose sulfuric acid from sulfur trioxide: A highly efficient catalyst for the one step synthesis of xanthene and dihydroquinazolinone derivatives
Yue, Xiaofei,Wu, Zhiqiang,Wang, Gang,Liang, Yanping,Sun, Yanyan,Song, Manrong,Zhan, Haijuan,Bi, Shuxian,Liu, Wanyi
, p. 28718 - 28723 (2019/09/30)
A cellulose sulfonate catalyst (HS-cellulose sulfonate) with high stability, excellent catalytic activity and high acidity value (about 1.55 mmol g-1) was successfully prepared by SO3 gas phase sulfonation. The basic morphology and nanostructure of the catalyst were determined by HRTEM, XRD, IR, TG, etc. In addition, the catalyst was applied to the catalytic reaction of a dihydroquinazolinone derivative and a xanthene compound, and very valuable results were obtained. The development and preparation of cellulose sulfonate catalysts provide a good approach for the development and application of cellulose, and also an important application of green organic catalytic synthesis methodology.
Introducing an effective nanocatalytic for the one-pot synthesis and investigation of biological properties of pyranopyrimidinone and xanthene derivatives
Amininia, A.,Pourshamsian, K.,Sadeghi, B.
, p. 4633 - 4638 (2020/04/30)
In this study, an effective method for the synthesis of pyranopyrimidinone and xanthene derivatives is introduced. In this method, zinc oxide-chitosan nanocomposite has been used as a catalyst and all reactions were performed under irradiated in a microwa
