37097-17-9

Upstream product

• 123-08-0 4-hydroxy-benzaldehyde 
• 135-19-3 β-naphthol 
• 16435-03-3 4-((2-phenylhydrazono)methyl)phenol 
• 93-09-4 naphthalene-2-carboxylate 

Relevant academic research and scientific papers

Solvent-free synthesis of 14-aryl-14H-dibenzo[a-j]xanthenes using Fe3O4@Al2O3@SiO2@Fe2O3 as a green catalyst

We report, a novel, green, nano-sized particles as a sandwich nano-capsule multilayer catalyst (SNC@MC) [Fe3O4@Al2O3@SiO2@Fe2O3] for the efficacious one-pot synthesis of 14-aryl-

Alkene-modified Fe3O4 nanoparticle-mediated construction of functionalized mesoporous poly(ionic liquid)s: Synergistic catalysis of mesoporous confinement effect and hydrogen proton for organic transformations

The preparation of mesoporous poly(ionic liquid)s (MPILs) is critically fundamental for the design of heterogeneous catalysts, whereas traditional methods are difficult to obtain these materials with both well-defined mesoporous structure and unique functionality. Here, HClO4-functionalized MPILs with well-defined mesoporous structure were successfully fabricated, in which the alkene-modified Fe3O4 nanoparticles as structural reinforcer play a vital role for mesoporous structure formation. The MPILs were characterized by N2 adsorption/desorption, scanning electron microscope (SEM), transmission Electron Microscope (TEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and vibration sample magnetometry (VSM), and the results confirm that MPILs possess moderate surface area, well-defined mesoporosity, abundant active ionic centers, as well as efficient magnetic recovery. The resulting MPILs show excellent catalytic activity for condensation reaction and Knoevenagel condensation. The kinetic study reveals that the excellent catalytic activity of MPILs is attributed to the synergistic catalysis of mesoporous confinement effect and hydrogen proton from MPILs, albeit with mass transfer resistance produced by mesoporous channels. Further, the catalyst can be recovered using an external magnetic field and reused at least 10 times without a considerable decrease in its catalytic activity. Finally, alkene-modified Fe3O4 nanoparticle-mediated mesoporous construction promotes a textural engineering approach to the development of novel mesoporous materials for other applications.

A rapid and quantitative synthesis of xanthene derivatives using sulfonated graphitic carbon nitride under ball‐milling

A truly green, solventless, and fast protocol for the quantitative preparation of biologically active xanthene derivatives with 10 mol% sulfonated graphitic carbon nitride (Sg─CN) as a heterogeneous acidic catalyst was developed. Excellent yields, low cost, solvent‐free conditions, high catalytic activity, reusability of the catalyst, simple workup, and heterogeneous carbon‐based catalyst make the present method particularly attractive from a green chemistry perspective.

Sulfamic acid functionalized 3D-network nanoporous polymer based on calix[4]resorcinarene: a recyclable heterogeneous nanocatalyst for the efficient synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes under thermal neat conditions

Abstract: The new synthesized sulfamic acid functionalized catalyst on the basis of calix[4]resorcinarene catalyzed successfully and efficiently the synthesis of 14-aryl-14H-dibenzo[a,j]xanthene derivatives through a one-pot condensation reaction of β-nap

Nano nickel-cobalt ferrite catalyzed one pot synthesis of 14-Aryl-14H-dibenzo[a, j]xanthenes and 12-Aryl-8, 9, 10, 12-tetrahydrobenzo[a]xanthene-11-one derivatives

A simple, green and multi component, one pot synthesis of 14-Aryl-14H-dibenzo[a, j]xanthene derivatives by condensation of aryl aldehydes with 2-naphthol using magnetically separable and recyclable heterogeneous catalyst nano nickel cobalt ferrite (Nisub

Sulfonated starch nanoparticles: An effective, heterogeneous and bio-based catalyst for synthesis of 14-aryl-14-H-dibenzo[a,j]xanthenes

In recent years, biodegradable polymer based nanoparticles have attracted wide attention for the synthesis of high-performance and green catalytic species. Polymeric nanoparticles used for catalytic processes must be biocompatible and biodegradable. The o

Metal free Lewis acid promoted one-pot synthesis of 14-aryl-14H dibenzo [a,j] xanthenes and their simple biological evolution

A green, competent one-pot synthesis of 14-aryl 14H-dibenzo [a,j] xanthene and its bio-computational studies are reported. Target compounds are prepared by the condensation of 2-naphthol with benzaldehyde and its substituents using metal free benzyltrimet

Fe+3-montmorillonite K10 as an Efficient Reusable Heterogeneous Catalyst for the Grind Mediated Synthesis of 14-aryl-14H-dibenzo [a,j]xanthenes

Background: Xanthenes are an important class of organic compounds and have also received significant attention due to their wide range of pharmacological activities such as antibacterial, antiviral, antiinflammatory activities, antagonists for the paralyzing action of zoxazolamine and efficiency in photodynamic therapy, a well-known method for controlling the localized tumors. Natural sources are also rich of xanthene compounds. Popularly known pigments, santalin have been isolated from plant species. Furthermore, these compounds can be emerged as pH-sensitive fluorescent materials for visualization of biomolecules, in laser technologies and as dyes. There are several reports in the literature for the synthesis of xanthenes such as alkylations of heteroatoms, cyclodehydrations, cyclocondensations between 2-hydroxyaromatic aldehydes and 2- tetralone, trapping of benzynes by phenols and intramolecular phenyl-carbonyl coupling reactions of benzaldehydes and acetophenones bearing tethered carbonyl chains in the presence of hexamethylphosphoramide and SmI2. Other methods for the synthesis of xanthenes include the reaction of formamide with β-naphthol, carbon monoxide, and 1- hydroxymethyl-naphthalen-2-ol. Methods: procedure a: A mixture of substituted benzaldehyde, 2-naphtol and Fe+3-montmorillonite K10 was mixed. After completion of the reaction, the product was solved in CHCl3 (3×10 mL) and insoluble catalyst was removed by filtration. The organic phase including the product and chloroform was evaporated under vacuum. The resulting crude material was purified by recrystallization from EtOH to afford pure products. procedure b: A mixture of substituted benzaldehyde, phenylhydrazine and Fe+3-montmorillonite K10 were added to a mortar and the mixture was pulverized with a pestle. After completion of the reaction, 2-naphtol was added to the consulting mixture and pulverized with a pestle. The organic phase including the product and chloroform was evaporated under vacuum. The resulting crude material was purified by recrystallization from EtOH to afford pure products. Results: As part of our going interest for the development of efficient and environmentally friendly procedures for the synthesis of heterocyclic and pharmaceutical compounds, we wish to report the first grind mediated synthesis of some derivatives of xanthenes using catalytic amount of Fe+3-montmotillonite. Conclusion: In conclusion, we have investigated the Fe+3-montmorillonite K10 under grinding as a mild and efficient catalyst for the synthesis of substituted 14-aryl-14H-dibenzo [a,j]xanthenes. The remarkable advantages offered by this method are: catalyst is inexpensive, non-toxic, easy handling and reusability, simple work-up procedure, short reaction time, high yields of product with better purity and green aspect by avoiding toxic catalyst and hazardous solvent.