37150-70-2Relevant academic research and scientific papers
Efficient Syntheses of Multisubstituted Methylenecyclopropanes via Novel Ultrasonicated Reactions of 1,1-Dihaloolefins and Metals
Xu, Linxiao,Lin, Guoying,Tao, Fenggang,Brinker, Udo H.
, p. 650 - 653 (2007/10/02)
Ultrasonicated reactions of 1,1-dihaloolefins with lithium, magnesium or sodium in the presence of alkenes rapidly afford multisubstituted methylenecyclopropanes.
Mild Generation of Alkylidenecarbenes from (Tosylazo)alkenes and Silylvinyl Triflates. Mode of Decomposition and Nature of the Carbene Intermediates
Fox, Dennis P.,Bjork, Jon A.,Stang, Peter J.
, p. 3994 - 4002 (2007/10/02)
(Tosylazo)alkenes, R2C=CHN=NTs, decomposed in olefin-solvent mixtures both under neutral conditions at room temperature and with amine bases present to produce alkylidenecyclopropanes in moderate to good yields.Diazoalkenes, R2C=C=N2, were implicated as t
