371968-42-2

Upstream product

• 371968-41-1 1,3,5-tris(4-bromobutyl)benzene 
• 1733-57-9 ethydiphenylphosphine oxide 
• 719-80-2 Ethyl diphenylphosphinite 
• 108-67-8 1,3,5-trimethyl-benzene 

Downstream Products

• 371968-43-3 1,3,5-tris[4'-(diphenylphosphanyl)butyl]benzene 

Relevant academic research and scientific papers

Trifunctional phosphane ligands and their application in the synthesis of novel cage-structured platinacyclophanes and trinuclear chain-like platinacycles by self-assembly

The synthesis of the 1,3,5-tris[(diphenylphosphoryl)alkyl]-benzenes 7-10 succeeds by reaction of the corresponding 1,3,5-tris(bromoalkyl)benzenes 3-6 with ethyl diphenylphosphinite in an Arbusov-type reaction. Reduction of these phosphane oxides leads to the trifunctional phosphane ligands 11-14. Their potency of self-assembly was examined by the employment of platinum(II) complex fragments. A five-component self-assembly consisting of 3 equiv, of the platinum complex Cl2Pt(NCPh)2 and 2 equiv, of the ligands 11-14 under high-dilution conditions led to the formation of the nanoscaled triplatinacyclophanes 1 and 15-17. Polymers were formed as by-products from the reactions between 11-13 and Cl2Pt(NCPh)2, whereas in the case of 14 three other platinacyles 18-20 with a chain-like structure were formed. The structures of the metallacycles 1 and 15-17 as well as 18-20 were elucidated by 31p{1H}, 13C{1H}, and 195Pt{1H} NMR spectroscopic investigations.

Preparation, properties, and reactions of metal-containing heterocycles, 102[1] a three-dimensional triplatinacyclophane with an eleven-membered bridge

Synthesis of 1,3,5-tris(4′-bromobutyl)benzene has been achieved by means of two step reaction. This compound reacts with ethyl diphenylphosphonic ester to form phosphoryl oxide which transformed to tertiary phosphine ligand. Employing the high dilution method from the ligand and Cl2Pt(NCPh)2 a cage compound is formed.