372189-22-5Relevant academic research and scientific papers
Palladium-catalyzed asymmetric allylic alkylation using chiral aminophosphine ligands
Mino, Takashi,Tanaka, Yoh-ichi,Akita, Koji,Anada, Kouhei,Sakamoto, Masami,Fujita, Tsutomu
, p. 1677 - 1682 (2007/10/03)
Palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate 18 with a dimethyl malonate-BSA-LiOAc system has been successfully carried out in the presence of new chiral aminophosphine ligands 1-5 in good yields with good enantioselectivities (up to 85% e.e.).
