372189-24-7Relevant academic research and scientific papers
Development of chiral (S)-prolinol-derived ligands for palladium-catalyzed asymmetric allylic alkylation: Effect of a siloxymethyl group on the pyrrolidine backbone
Tanaka, Youichi,Mino, Takashi,Akita, Koji,Sakamoto, Masami,Fujita, Tsutomu
, p. 6679 - 6687 (2007/10/03)
A series of novel chiral aminophosphine ligands are designed and readily prepared from (S)-prolinol. The reactivity and selectivity in the palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate with a dimethyl malonate-BSA-Li
Palladium-catalyzed asymmetric allylic alkylation using chiral prolinol-derived aminophosphine ligands
Mino, Takashi,Tanaka, Youichi,Akita, Koji,Sakamoto, Masami,Fujita, Tsutomu
, p. 9 - 13 (2007/10/03)
Palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate (4) with a dimethyl malonate-BSA-LiOAc system has been successfully carried out in the presence of a new chiral prolinol-derived aminophosphine ligand (3e) in good yield
Palladium-catalyzed asymmetric allylic alkylation using chiral aminophosphine ligands
Mino, Takashi,Tanaka, Yoh-ichi,Akita, Koji,Anada, Kouhei,Sakamoto, Masami,Fujita, Tsutomu
, p. 1677 - 1682 (2007/10/03)
Palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate 18 with a dimethyl malonate-BSA-LiOAc system has been successfully carried out in the presence of new chiral aminophosphine ligands 1-5 in good yields with good enantioselectivities (up to 85% e.e.).
