374-59-4Relevant academic research and scientific papers
Free radical chemistry. Part 10.1 Addition of acyclic and cyclic alkanes to hexafluoropropene
Chambers, Richard D.,Fuss, Robert W.,Spink, Robert C. H.,Greenhall, Martin P.,Kenwright, Alan M.,Batsanov, Andrei S.,Howard, Judith A. K.
, p. 1623 - 1638 (2007/10/03)
γ-Ray or peroxide initiated reactions of acyclic and cyclic alkanes with hexafluoropropene are described. A variety of perfluorocarbons and polyfluorinated alkenes, di-enes and a tetra-ene were synthesised from these polyfluoroalkylated alkanes. Eliminati
THE SYNTHESIS OF HIGHLY FLUORINATED ALKYLCYCLOHEXANES FOR USE AS OXYGEN CARRIERS AND THE 19F AND 13C NMR SPECTRA OF ALKYLCYCLOHEXANES
Lin, Wen-Huey,Lagow, Richard J.
, p. 345 - 358 (2007/10/02)
Perfluoroalkylcyclohexanes are promising candidates for oxygen carriers.The perfluoroalkylcyclohexane analogues and 1H-perfluoroalkylcyclohexanes of n-propylcyclohexane, i-propylcyclohexane, n-butylcyclohexane, s-butylcyclohexane, i-butylcyclohexane and t-butylcyclohexane were prepared and characterized.Their properties and NMR spectra are discussed.
FREE RADICAL CHEMISTRY, PART 5. A NEW APPROACH TO THE SYNTHESIS OF PERFLUORINATED ETHERS
Chambers, Richard D.,Grievson, Brian,Drakesmith, Frederick G.,Powell, Richard L.
, p. 323 - 340 (2007/10/02)
Fluorinations of the free-radical adducts of fluorinated alkenes, to ethers, over cobalt trifluoride are described and perfluorinated ethers are obtained at temperatures in excess of 400 deg C.The effect of structure on the formation of perfluoroethers is outlined.
