37428-63-0Relevant academic research and scientific papers
Oxidative degradation of oligo(ethylene glycol)-terminated monolayers
Qin, Guoting,Cai, Chengzhi
supporting information; experimental part, p. 5112 - 5114 (2009/12/08)
The observation that oligo(ethylene glycol) (OEG)-terminated monolayers remained highly protein-resistant for a month at 37 °C in PBS buffer while they degraded faster in air can be rationalized by a proposed mechanism formulated from a model study using
Reductive O- and N-alkylations. Alternative catalytic methods to nucleophilic substitution
Fache, Fabienne,Bethmont, Valerie,Jacquot, Laurent,Lemaire, Marc
, p. 231 - 238 (2007/10/03)
Different amides have been selectively mono-N-alkylated using catalytic heterogeneous palladium and carbonyl compounds as alkylating agents. The same salt free method has been applied to the synthesis of ethers from alcohols. Reaction parameters have been studied in detail and a mechanism is proposed.
An alternative catalytic method to the Williamson's synthesis of ethers
Bethmont, Valerie,Fache, Fabienne,Lemaire, Marc
, p. 4235 - 4236 (2007/10/02)
The synthesis of ethers from alcohols and aldehydes or ketones via the corresponding hemiketals is reported using Pd/C as catalyst, under hydrogen. Good isolated yield (> 80%) are obtained.
