374569-92-3

Basic information

• Product Name: supersilylaluminum dibromide
• CAS NO: 374569-92-3
• Molecular Weight: 386.221
• Mol File: 374569-92-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: supersilylaluminum dibromide(CAS DataBase Reference)
• NIST Chemistry Reference: supersilylaluminum dibromide(374569-92-3)
• EPA Substance Registry System: supersilylaluminum dibromide(374569-92-3)

Safety Data

• Hazardous Substances Data: 374569-92-3(Hazardous Substances Data)

Relevant articles and documents

NHC Supersilyl Silver Complex [Ag(IPr)SitBu3] as a Promising Agent for Substitution Reactions

The NHC supersilyl silver complex [Ag(IPr)SitBu3] (IPr = NHCIPr) was prepared by treatment of Ag(IPr)Cl with Na(thf)2[SitBu3] in benzene/thf at room temperature. X-ray quality crystals of the NHC supersilyl silver complex [Ag(IPr)SitBu3] (monoclinic, space group P21/m) were grown from heptane at room temperature. The 29Si NMR spectrum of a solution of [Ag(IPr)SitBu3] in C6D6 revealed two doublets caused by coupling to 107Ag and 109Ag nuclei. We further investigated the possibility of a conversion of triel halides EX3 by treatment with [Ag(IPr)SitBu3]. At ambient temperature the reaction of [Ag(IPr)SitBu3] with an excess of EX3 yielded tBu3SiEX2 (E = B, Al; X = Cl, Br; E = Ga; X = Cl) and IPr·EX3 (EX3 = BCl3, BBr3, AlCl3, AlBr3, GaCl3). The identity of tBu3SiEX2 and IPr·EX3 was confirmed by comparison with authentic samples.