37457-18-4

Upstream product

• 78707-70-7 (2S,3R)-3-(1,1-Bis-methylselanyl-ethyl)-2-methyl-cyclohexanone 
• 89969-07-3 (2R,3S)-2-Methyl-3-(1-methylselanyl-vinyl)-cyclohexanone 
• 78707-70-7 (2R,3R)-3-(1,1-Bis-methylselanyl-ethyl)-2-methyl-cyclohexanone 
• 1121-18-2 2-methyl-2-cyclohexen-1-one 

Downstream Products

• 64811-81-0 1-(2-methylcyclohexyl)ethanone 
• 63196-65-6 (Z)-non-7-en-2-one 
• 25143-93-5 non-7t-en-2-one 

Relevant academic research and scientific papers

Clemmensen Reduction. XI. Fragmentation Reactions of Some 3-Acetylcycloalkanones

Clemmensen reduction of a series of 3-acetylcycloalkanones yields, as the major product, an acyclic unsaturated ketone, the product of fragmentation.Some normal carbonyl-methylene reduction also occurs.A mechanistic rationale for the fragmentation is advanced.

REGIOSELECTIVE SYNTHETIC ROUTES TO 1,4-DICARBONYL COMPOUNDS AND SOME α-HYDROXY CARBONYL COMPOUNDS FROM 1,1-BIS(THIO)- AND BIS(SELENO)-ALLKYLLITHIUMS

CuCl2/CuO was found to be a particularly valuable combination for the transformation of functionalized thio- and seleno-ketals to the corresponding aldehydes and ketones.