374573-45-2

Upstream product

• 132183-14-3 (2R,3R,4R,5R,6S)-2-(acetoxymethyl)-5-azido-6-((tert-butyldiphenylsilyl)oxy)tetrahydro-2H-pyran-3,4-diyl diacetate 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 132183-15-4 tert-butyldiphenylsilyl 2-azido-2-deoxy-β-D-galactopyranoside 
• 77-76-9 2,2-dimethoxy-propane 

Downstream Products

• 906794-61-4 acetic acid 2-(7-amino-2,2-dimethyl-6-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-4-yl)-1-[3,4-bis-(tert-butyl-dimethyl-silanyloxy)-5-(2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-furan-2-yl]-ethyl ester 
• 719278-96-3 1-[(2R,3R,4R,5R)-5-[(R)-2-((3aS,4R,6S,7R,7aR)-7-Azido-2,2-dimethyl-6-phenylsulfanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-4-yl)-1-hydroxy-ethyl]-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-furan-2-yl]-1H-pyrimidine-2,4-dione 
• 719278-93-0 1-[10-azido-2,3-di-O-(tert-butyldimethylsilyl)-6,10,11-trideoxy-8,9-O-isopropylidene-11-S-phenyl-11-thio-L-lyxo-D-allo-undeculofuranosyl-(1,4)]uracil 
• 719278-87-2 tert-butyldiphenylsilyl 2-azido-2-deoxy-3,4-O-isopropylidene-6-S-phenyl-6-thio-β-D-galactopyranoside 
• 719278-90-7 (2S,3R,4S,5R)-2-azido-5-benzoyloxy-3,4-(dimethylmethylenedioxy)-1,6-di(phenylthio)hexane 
• 719278-89-4 (2S,3R,4S,5R)-2-azido-5-benzoyloxy-3,4-(dimethylmethylenedioxy)-6-phenylthio-1-hexanol 
• 719278-91-8 (2S,3R,4S,5R)-2-azido-3,4-(dimethylmethylenedioxy)-1,6-di(phenylthio)hexane 
• 719278-92-9 (3R,4R,5S)-5-azido-3,4-(dimethylmethylenedioxy)-1,6-di(phenylthio)-2-hexanone 
• 719278-88-3 (2S,3R,4S,5R)-2-azido-3,4-(dimethylmethylenedioxy)-6-phenylthio-1,5-hexanediol 

Relevant academic research and scientific papers

Synthesis of Tunicaminyluracil Derivatives

A tunicaminyluracil derivative, which is a key component of the tunicamycin nucleoside antibiotics, was synthesized using a samarium diiodide (Sml2) mediated aldol reaction and intramolecular Pummerer reaction as the key steps. The α-phenylthio