374592-20-8

Basic information

• Product Name: 3-[(1S,6R)-3,4-Dimethyl-6-((1R,2R,3R,4R)-1,2,3,4,5-pentahydroxy-pentyl)-cyclohex-3-enyl]-propionic acid methyl ester
• CAS NO: 374592-20-8
• Molecular Weight: 346.421
• Mol File: 374592-20-8.mol

Chemical Properties

• CAS DataBase Reference: 3-[(1S,6R)-3,4-Dimethyl-6-((1R,2R,3R,4R)-1,2,3,4,5-pentahydroxy-pentyl)-cyclohex-3-enyl]-propionic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-[(1S,6R)-3,4-Dimethyl-6-((1R,2R,3R,4R)-1,2,3,4,5-pentahydroxy-pentyl)-cyclohex-3-enyl]-propionic acid methyl ester(374592-20-8)
• EPA Substance Registry System: 3-[(1S,6R)-3,4-Dimethyl-6-((1R,2R,3R,4R)-1,2,3,4,5-pentahydroxy-pentyl)-cyclohex-3-enyl]-propionic acid methyl ester(374592-20-8)

Safety Data

• Hazardous Substances Data: 374592-20-8(Hazardous Substances Data)

Upstream product

• 374592-17-3 3-[(1S,6R)-3,4-Dimethyl-6-((1R,2R,3R,4R)-1,2,3,4,5-pentaacetoxy-pentyl)-cyclohex-3-enyl]-propionic acid methyl ester 
• 217298-50-5 1',2',3',4',5'-penta-O-acetyl-1'-C-[(4S,5R)-1,2-dimethyl-4-(2''-methoxycarbonylethyl)-4-nitrocyclohex-1-en-5-yl]-D-manno-pentitol 

Relevant articles and documents

Stereoselective denitrohydrogenation reactions of 4-alkyl-5-glyco-4-nitrocyclohex-1-enes

The denitrohydrogenation of chiral 4-alkyl-5-glyco-4-nitrocyclohex-1-enes (1 and 3) with tri-n-butyltin hydride and azobisisobutironitrile proceeded in a completely stereoselective way. In each case, the hydrogen atom provided by tri-n-butyltin hydride adds to a free radical intermediate in a trans mode to the adjacent, sterically demanding, sugar side-chain. Attempts to perform denitroalkylation reactions of 1a, 3a or 8 with electron-deficient alkenes yielded only denitrohydrogenated products.