37504-61-3Relevant academic research and scientific papers
Preparation and reduction of rhodium(III) complexes of a quadridentate Schiff-base ligand, and synthesis of organo-rhodium(III) derivatives
Cozens,Murray,West
, p. 391 - 402 (1972)
The RhIII Schiff-base complexes RhSalenClPy and (PyH)(RhSalenCl2), and the RhIIRhII bonded dimer (RhSalenPy)2 have been prepared, and their probable structures and reactivities are discussed. RhSalenClPy has been reduced using both 0.2% sodium amalgam and NaBH4/PdCl2 to produce solutions containing mono- and di-sodium derivatives, and the di-sodium derivative has been treated with a number of organic halides to yield a series of derivatives of the general formula R-RhSalenPy (R=CH3, C2H5, n-C3H7, i-C3H7, n-C4H9, CH3CO, CH2CHCH2 and C6H5CH2). Spectral evidence confirms that these derivatives are RhC bonded.
