37516-15-7

Upstream product

• 392-56-3 Hexafluorobenzene 
• 1499-33-8 triphenylmethylarsonium iodide 
• 104-88-1 4-chlorobenzaldehyde 
• 1073-67-2 4-vinylbenzyl chloride 
• 832-53-1 pentafluorobenzenesulonyl chloride 
• 602-94-8 Pentafluorobenzoic acid 
• 2065-66-9 methyl-triphenylphosphonium iodide 

Relevant academic research and scientific papers

Substrate-Dependent Mechanistic Divergence in Decarboxylative Heck Reaction at Room Temperature

We report herein a Pd(II)-catalyzed Heck-type coupling between arene carboxylic acids and alkenes at room temperature. Mechanistically, the reaction proceeds in two distinct pathways where electron-rich substrates undergo a palladium(II)-catalyzed decarboxylation and electron-deficient substrates proceed through silver(I)-assisted decarboxylation. Dimethyl sulfoxide (DMSO) or sulfide ligands have positive and negative roles in the reaction outcome, respectively. The present protocol is combined for the peptide modification under mild reaction conditions.

Reactions of pentafluorobenzenesulfonyl chloride with alkenes in the presence of a ruthenium or palladium complex

The reactions of pentafluorobenzenesulfonyl chloride with styrenes in the presence of a ruthenium(II) phosphine complex and subsequent treatment with tnethylamine were found to give (E)-1-aryl-2-(pentafluorobenzenesulfonyl)ethene in high yields. On the ot

A Facile Synthesis of Pentafluorophenyl Olefins via an Arsonium Ylide

The in situ reaction of (pentafluorophenylmethylene)triphenylarsorane, generated from methylenetriphenylarsorane and hexafluorobenzene, with aromatic aldehydes gives good to excellent yields of pentafluorophenyl olefins with high stereoselectivity.