375367-28-5Relevant academic research and scientific papers
1,4-Addition of chiral 2-propenylphosphonamide anions to α-substituted cyclopentenones: Use in enantioselective syntheses of methyl dihydrojasmonates and methyl jasmonates
Hailes, Helen C.,Isaac, Ben,Javaid
, p. 7325 - 7328 (2001)
The addition of chiral 2-propenylphosphonamide anions, generated from the reaction products of (1R,2S)-ephedrine and 2-propene-1-phosphonyl dichloride, to α-substituted cyclopentenones is described. Ozonolysis of the addition products led to the synthesis of both enantiomers of methyl dihydrojasmonate and methyl jasmonate.
