375388-40-2Relevant academic research and scientific papers
Effective control of two elimination processes from a hydridobis(silyl)iron(IV) complex
Sato, Takahiro,Tobita, Hiromi,Ogino, Hiroshi
, p. 854 - 855 (2001)
A novel hydridobis(silyl)iron(IV) complex Cp*(CO)Fe(H)-(SiMe2O(2-C5H4N)}2 (1) (Cp=η5-C5Me5) was synthesized in high yield. Two elimination processes from 1 were effectively controlled by the reaction conditions: HSiMe2O(Z-C5H4N) is eliminated on heating or UV-irradiation, whereas HO(2-C5H4N) is eliminated in the presence of Et3Al. The latter reaction was applied to a silylene introduction toward a silyl complex producing a silyl(silylene) complex.
