37575-87-4Relevant academic research and scientific papers
Organometallic Compounds. XI. Chlorotrimethylsilane / Sodium Bromide - A Simple System for the in situ Generation of Bromotrimethylsilane. Reaction with Ketones, Sulfoxides, and Various Oxygen Containing Substrates
Schmidt, Arthur H.,Russ, Manuel
, p. 1099 - 1110 (2007/10/02)
Bromotrimethylsilane is generated in situ by the addition of chlorotrimethylsilane (2) to a solution or a suspension of sodium bromide (or LiBr, KBr, MgBr2).The reaction of the in situ generated bromotrimethylsilane with ketones, sulfoxides, γ-butyrolactone, triethyl orthoformate, and trialkyl phosphites is described.
