37631-34-8Relevant academic research and scientific papers
Isolation, X-ray crystal structure, and reactivity of a new C-H carbene complex of (5,10,15,20-tetraphenylporphyrinato)ruthenium(II)
Maux, Paul Le,Roisnel, Thierry,Nicolas, Irene,Simonneaux, Gerard
, p. 3037 - 3042 (2008)
The new (porphyrin)ruthenium(II) carbene complex 1 has been prepared by treating (TPP)Ru(CO)(EtOH) with excess 2,6-di-tert-butyl-4-methylphenyl diazoacetate and characterized by X-ray crystal structure analysis due to a kinetic stability. The reactivity of 1 toward axial ligands (CO, pyridine, dimethylphenylphosphine) and the asymmetric cyclopropanation of styrene with this bulky diazoacetate ester catalyzed by ruthenium Halterman porphyrin are also presented.
