376646-84-3

Upstream product

• 96090-12-9 p-bromo-cinnamyl bromide 
• 1730-25-2 allylmagnesium bromide 
• 1204403-30-4 1-(4-bromophenyl)allyl isopropyl carbonate 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Relevant academic research and scientific papers

Copper-catalyzed enantioselective allyl-allyl cross-coupling

A Cu(I)-phosphoramidite-based catalytic system that allows asymmetric allyl-allyl cross-coupling with high enantioselectivity is reported. This transformation tolerates a large variety of functionalized substrates. The versatility of this new reaction is illustrated in the catalytic asymmetric synthesis of the Martinelline alkaloids chromene derivative core.

Palladium(0) versus nickel(0) catalysis in selective functional- grouptolerant sp3-sp3 carbon-carbon bond formations

We have uncovered Pd°-catalyzed intermolecular nonsymmetrical Suzuki-Miyaura-type sp3-sp3 C-C bond formations between allyl carbonates and nontoxic allyl, allenyl, or propargyl boronates. This report represents the first use of these