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3768-55-6

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3768-55-6 Usage

General Description

N-Trimethylsilylaniline is a synthetic chemical compound that is characterized by the presence of silicon, nitrogen, hydrogen, and carbon atoms. As a derivative of aniline, it plays a significant role in the synthesis of organic and especially organosilicon compounds. It is primarily used in the production of pharmaceuticals, dyes, and plastics as it exhibits essential properties like resistance to heat and electricity. Handling this chemical requires caution as it is known for its flammable nature and potential to cause skin, eye, and respiratory tract irritation upon exposure. It is stored in cool, dry, and well-ventilated areas to prevent any hazardous situations.

Check Digit Verification of cas no

The CAS Registry Mumber 3768-55-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,7,6 and 8 respectively; the second part has 2 digits, 5 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 3768-55:
(6*3)+(5*7)+(4*6)+(3*8)+(2*5)+(1*5)=116
116 % 10 = 6
So 3768-55-6 is a valid CAS Registry Number.
InChI:InChI=1/C9H15NSi/c1-11(2,3)10-9-7-5-4-6-8-9/h4-8,10H,1-3H3

3768-55-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name N-TRIMETHYLSILYLANILINE

1.2 Other means of identification

Product number -
Other names phenyltrimethylsilylamine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3768-55-6 SDS

3768-55-6Relevant articles and documents

Formation of Aromatic O-Silylcarbamates from Aminosilanes and Their Subsequent Thermal Decomposition with Formation of Isocyanates

Gründler, Franziska,Herbig, Marcus,Kroke, Edwin,Scholz, Henrik,Schwarzer, Sandra,Wagler, J?rg

, p. 2211 - 2224 (2021/06/11)

A novel phosgene-free route to different isocyanates starts from CO2 and aminosilanes (cf. silylamines) to form so-called carbamoyloxysilanes (O-silylcarbamates), i. e., compounds with the general motif R1R2N?CO?O?SiR3R4R5 as potential precursors. We focused on the insertion reaction of CO2 into Si?N bonds of substrates with cyclic (mostly aromatic) amine substituents, i. e., PhNHSiMe3, (PhNH)2SiMe2, PhCH2NHSiMe3, p-(MeO)C6H4NHSiMe3, o-C6H4(NHSiMe3)2, 1,2-C6H10(NHSiMe3)2, o-C6H4(NHSiMe3)(CH2NHSiMe3) and 1,8-C10H6(NHSiMe3)2. Compared to previously investigated aminosilanes these reactions are hindered due to the reduced nucleophilicity/basicity of the N-atoms. Whereas slightly increased CO2 pressure (8 bar) and prolonged reaction times (24 h) were sufficient to overcome hindrance of the insertion into, e. g., PhNHSiMe3, intermolecular effects in some two-fold NHSiMe3 functionalized substrates led to partial mono-insertion (e. g., into o-C6H4(NHSiMe3)(CH2NHSiMe3)) or intra-molecular condensation of the intermediate insertion product in case of 1,8-C10H6(NHSiMe3)2 to form 1H-perimidin-2(3H)-one and other side products. Thermal treatment of mono-silylated O-silylcarbamates RHN?CO?O?SiR’3 resulted mainly in the formation of substituted ureas (RHN)2CO, whereas desired isocyanates could not be detected in these cases. Therefore, we continued our studies focussing on N,O-bissilylated precursors, which were obtained by an additional N-silylation of the O-silylated carbamates. This allowed the successful formation of isocyanates. As a sole byproduct hexamethyldisiloxane is formed. In all cases, known as well as yet unknown substances were characterised by 1H, 13C and 29Si NMR spectroscopy, along with X-ray diffraction analysis for crystallized solids.

Trimethylsilyl-Induced N-O Bond Cleavage in Nitrous Oxide-Derived Aminodiazotates

Liu, Yizhu,Eymann, Léonard Y. M.,Solari, Euro,Fadaei Tirani, Farzaneh,Scopelliti, Rosario,Severin, Kay

, p. 11859 - 11863 (2018/09/25)

The chemical activation of nitrous oxide (N2O) typically results in O-atom transfer and the extrusion of N2 gas. In contrast, reactions of N-trimethylsilyl (TMS)-substituted amides with N2O give inorganic or organic azides

Ruthenium-catalyzed dealkenative N-silylation of amines by substituted vinylsilanes

Marciniec, Bogdan,Kostera, Sylwia,Wyrzykiewicz, Bozena,Pawlu, Piotr

supporting information, p. 782 - 786 (2015/02/19)

The ruthenium hydride complex-catalyzed N-silylation of primary and secondary amines with substituted vinylsilanes, with the general formula R1CHCHSiR′3 (where R1 = H, Ph, n-Bu, Si(OEt)3), leading to the formation of a Si-

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