37696-13-2

Upstream product

• 3886-69-9 (R)-1-phenyl-ethyl-amine 
• 75-07-0 acetaldehyde 

Downstream Products

• 131703-36-1 2-<(1-phenylethyl)amino>propanenitrile 
• 348608-04-8 (+)-N-[(R)-α-methylbenzyl]-pent-1-ene-4-amine 
• 70811-66-4 (R)-N-ethyl-α-methylbenzenemethanamine 
• 133693-74-0 trans-(3R,4R)-1(R)-(α-methylbenzyl)-3-<(methoxycarbonyl)amino>-4-methyl-2-azetidinone 
• 133774-23-9 cis-(3R,4S)-1(R)-(α-methylbenzyl)-3-<(methoxycarbonyl)amino>-4-methyl-2-azetidinone 
• 141040-15-5 trans-(3S,4S)-1(R)-(α-methylbenzyl)-3-<(methoxycarbonyl)amino>-4-methyl-2-azetidinone 
• 141040-14-4 cis-(3S,4R)-1(R)-(α-methylbenzyl)-3-<(methoxycarbonyl)amino>-4-methyl-2-azetidinone 
• 133774-21-7 cis-(3R,4S)-1(R)-(α-methylbenzyl)-3-(2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopentyl)-4-methyl-2-azetidinone 
• 133693-71-7 trans-(3R,4R)-1(R)-(α-methylbenzyl)-3-(2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopentyl)-4-methyl-2-azetidinone 
• 141040-07-5 cis-(3S,4R)-1(R)-(α-methylbenzyl)-3-(2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopentyl)-4-methyl-2-azetidinone 
• 141040-08-6 trans-(3S,4S)-1(R)-(α-methylbenzyl)-3-(2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopentyl)-4-methyl-2-azetidinone 
• 133693-72-8 trans-(3R,4R)-1(R)-(α-methylbenzyl)-3-amino-4-methyl-2-azetidinone 
• 133774-25-1 cis-(3R,4S)-1(R)-(α-methylbenzyl)-3-amino-4-methyl-2-azetidinone 
• 141040-11-1 trans-(3S,4S)-1(R)-(α-methylbenzyl)-3-amino-4-methyl-2-azetidinone 

Relevant academic research and scientific papers

Synthesis of lactams by radical substitution reaction of α,β-unsaturated acyl radicals at amine nitrogen

(Chemical Equation Presented) Substitution at nitrogen by α,β-unsaturated acyl radicals took place accompanied by elimination of an α-phenethyl radical. This reaction led to the development of a new carbonylative annulation method for five- to seven-membe

Diastereoselective carbozincation of propargylic amines

The carbometalation of propargylic amines derived from methylbenzylamine takes place with good 1,3-diastereoselection in the presence of Lewis acids.

Asymmetric Syntheses of Amino Acids by Addition of Cyanide to the Schiff Bases in the Presence of Cyanide-Modified Hemin-Copolymer

Sterically controlled addition reactions of CN group to the Schiff bases by using CN-modified hemin-copolymer were carried out, and the optical yields (80-95 e.e.) of the resulting amino acids were much higher than that obtained without hemin-copolymer.

ASYMMETRIC ADDITION OF TRIS(TRIMETHYLSILYL) PHOSPHITE TO CHIRAL ALDIMINES

Addition of tris(trimethylsilyl) phosphite (2) to (+)-(R)-1-phenylethylaldimines (1) and methanolysis of addition products affords(+)-N-(1-phenyethyl)-1-aminoalkanophosphonic acids (3).Chemical yields and diastereomeric composition of 3 vary from 10 to 90