37699-98-2Relevant academic research and scientific papers
Microwave-assisted cyclizations promoted by polyphosphoric acid esters: A general method for 1-aryl-2-iminoazacycloalkanes
Díaz, Jimena E.,Mollo, María C.,Orelli, Liliana R.
supporting information, p. 2026 - 2031 (2016/10/05)
The first general procedure for the synthesis of 5 to 7-membered 1-aryl-2-iminoazacycloalkanes is presented, by microwave-assisted ring closure of ω-arylaminonitriles promoted by polyphosphoric acid (PPA) esters. 1-Aryl-2-iminopyrrolidines were easily pre
1,n-diamines. Part 2: Synthesis of acyclic and heterocyclic N-arylputrescine derivatives
Díaz, Jimena E.,Bisceglia, Juan á.,Mollo, Ma. Cruz,Orelli, Liliana R.
supporting information; experimental part, p. 1895 - 1897 (2011/04/25)
In the present Letter we report the use of N-arylputrescines as synthetic intermediates for the preparation of N-acyl-N′-aryltetramethylenediamines 3 and related seven-membered heterocyclic amidines 4. Compounds 1 were synthesized by Cs2CO
1,n-Diamines. Part 4: Synthesis of 1-aryl-2-alkyl-1,4,5,6,7,8-hexahydro-1, 3-diazocines
Díaz, Jimena E.,Gruber, Nadia,Orelli, Liliana R.
supporting information; experimental part, p. 6443 - 6445 (2012/01/19)
In this Letter we present the synthesis of hitherto unreported 1-aryl-2-alkyl-1,4,5,6,7,8-hexahydro-1,3-diazocines 1. Cyclic amidines 1 were synthesized by PPSE promoted ring closure of N-acyl-N'-arylpen- tamethylenediamines 2. The cyclodehydration reacti
