37775-99-8Relevant academic research and scientific papers
CHIRAL PHOSPHORUS COMPOUNDS
-
Page/Page column 22-23; 26-27, (2010/02/15)
A process for the stereoselective preparation of a P-chiral four-co-ordinated phosphorus compound, the process comprising reacting a first reactant selected from the group consisting of a chiral alcohol, chiral amine or chiral thiol, with a second reactan
Kinetic resolution of racemic ferrocenylphosphine compounds by enantioselective oxidation using cyclic selenoxides having a chiral ligand
Miyake, Yoshihiro,Yamauchi, Akiyoshi,Nishibayashi, Yoshiaki,Uemura, Sakae
, p. 381 - 387 (2007/10/03)
Cyclic selenoxides having an optically active binaphthyl skeleton work as the reagents for enantioselective oxidation of phosphines to the corresponding phosphine oxides. Treatment of a racemic 2-oxazolin-2-ylferrocenylphosphine with one of the selenoxides in carbon tetrachloride in the presence of phenol affords the corresponding phosphine oxide together with the unreacted starting phosphine, both with moderate enantioselectivities (the phosphine oxide, up to 13% ee; the phosphine, up to 29% ee).
CYCLOMETALATION OF PHOSPHORUS LIGANDS BY UV IRRADIATION OF COMPLEXES HAVING TRANSITION METAL-SILICON BONDS
Cerveau, Genevieve,Chauviere, Gerard,Colomer, Ernesto,Corriu, J.P.
, p. 343 - 352 (2007/10/02)
UV irradiation of complexes of the type (η5-C5H5)(CO)nMSiR3 (n=2, M=Fe; n=3, M=Mo) in the presence of phosphorus ligands such as P(XC6H5)3 (X=O, S, CH2) and phosphines containing allyl, 1-naphthyl or tolyl groups gives cyclometalated complexes,
