37778-97-5Relevant academic research and scientific papers
Influence of a β-Alkoxy Substituent on the C-H Activation Chemistry of Alkyl Ethers
Davies, Huw M. L.,Yang, Jaemoon
, p. 1133 - 1138 (2003)
C-H activation reactions of 1,2-dimethoxyethane and methyl tert-butyl ether with methyl aryldiazoacetates or styryldiazoacetate catalyzed by Rh 2(S-DOSP)4 result in the formation of 2-aryl- or 2-styryl-substituted propanoic acids with asymmetric induction up to 95% ee.
Catalytic Enantioselective Protonation/Nucleophilic Addition of Diazoesters with Chiral Oxazaborolidinium Ion Activated Carboxylic Acids
Kang, Ki-Tae,Kim, Seung Tae,Hwang, Geum-Sook,Ryu, Do Hyun
, p. 3977 - 3981 (2017/03/27)
A new chiral Br?nsted acid derived from carboxylic acid and a chiral oxazaborolidinium ion (COBI), as an activator, is introduced. This acid was successfully applied as a catalyst for the highly enantioselective protonation/nucleophilic addition of diazoesters with carboxylic acids.
Asymmetric synthesis of (S)-(-)-methyl tropinate: Application of the iron acyl complex (S)-(+)-[(η5-C5H5)Fe(CO)(PPh3) COCH2Ph] as a homochiral phenylacetate enolate equivalent
Baker, Teresa M.,Bodwell, Graham J.,Davies, Stephen G.,Edwards, Alison J.,Metzler, Michael R.
, p. 5635 - 5647 (2007/10/02)
Treatment of the lithium enolate derived from homochiral (S)-[(η5-C5H5)Fe(CO)(PPh 3)COCH3 5 with benzyne afforded the homochiral phenylacetyl complex (S)-[(η5-C5H5)Fe(
