37818-31-8

Upstream product

• 718-64-9 1,1,1,3,3,3-hexafluoro-2-phenylisopropyl alcohol 

Downstream Products

• 69352-07-4 3,3-dimethyl-1-(2,2,2-trifluoro-1-phenyl-1-trifluoromethyl-ethoxy)-1,3-dihydro-1λ³-benzo[d][1,2]iodoxole 
• 69352-06-3 5-methyl-3,3-bis-trifluoromethyl-1-(2,2,2-trifluoro-1-phenyl-1-trifluoromethyl-ethoxy)-1,3-dihydro-1λ³-benzo[d][1,2]iodoxole 
• 52908-59-5 1-(2,2-Difluoro-1-trifluoromethyl-vinyl)-4-(2,2,2-trifluoro-1-phenyl-1-trifluoromethyl-ethoxy)-benzene 
• 32133-82-7 Martins sulfurane 
• 136213-52-0 1-fluoro-1-<2,2,2-trifluoro-1-phenyl-1-(trifluoromethyl)ethoxy>-10-tert-butyl-3,3,7,7-tetrakis(trifluoromethyl)-4,6-benzo-1-ioda-2,8-dioxabicyclo<3.3.0>octane 
• 57633-50-8 4-Chloro-benzoic acid 2,2,2-trifluoro-1-phenyl-1-trifluoromethyl-ethyl ester 
• 1439357-75-1 C₂₇H₁₅CuF₁₈O₃^(1-)*K⁽¹⁺⁾ 
• 40999-37-9 N-Isopropyl-benzimidic acid 2,2,2-trifluoro-1-phenyl-1-trifluoromethyl-ethyl ester 
• 40999-33-5 N-Butyl-benzimidic acid 2,2,2-trifluoro-1-phenyl-1-trifluoromethyl-ethyl ester 
• 40999-38-0 N-Butyl-2,2-dimethyl-propionimidic acid 2,2,2-trifluoro-1-phenyl-1-trifluoromethyl-ethyl ester 
• 54755-74-7 C₃₀H₁₉F₁₂NO₄S 
• 52908-58-4 1-(2,2,2-Trifluoro-1-phenyl-1-trifluoromethyl-ethoxy)-4-(2,2,2-trifluoro-1-trifluoromethyl-ethyl)-benzene 

Relevant academic research and scientific papers

K×××F/O interactions bridge copper(I) fluorinated alkoxide complexes and facilitate dioxygen activation

Seven E[Cu(OR)2] copper(I) complexes (E=K+, {K(18C6)}+ (18C6=[18]crown-6), or Ph4P+; R=C4F9, CPhMeF2, and CMeMe F2) have been prepared and their reactivity with O 2 studied. The K[Cu(OR)2] species react with O2 in a copper-concentration-dependent manner such that 2:1 and 3:1 Cu/O 2 adducts are observed manometrically at -78 °C. Analogous reactivity with O2 is not observed with the {K(18C6)}+ or Ph4P+ derivatives. Solution conductivity data demonstrate that these K[Cu(OR)2] complexes do not behave as 1:1 electrolytes in solution. The K+ ions induce aggregation of multiple [Cu(OR) 2]- units through K×××F/O interactions and thereby effect irreversible O2 reduction by multiple Cu centers. Bond valence analyses for the potassium cations confirm the dominance of the fluorine interactions in the coordination spheres of K+ ions. Intramolecular hydroxylation of ligand aryl and alkyl C-H bonds is observed. Nucleophilic reactivity with CO2 is observed for the oxygenated Cu complexes and a CuII carbonate has been isolated and characterized. Copyright