37844-95-4Relevant academic research and scientific papers
TRANSANNULAR IONIC HYDROGENATION, AND ACIDIC CYCLIZATION AND ISOMERIZATION REACTIONS OF 3,7-DIMETHYLENEBICYCLONONANE AND ITS DERIVATIVES
Krasutskii, P. A.,Ambrosienko, N. V.,Rodionov, V. N.,Yurchenko, A. G.,Parnes, Z. N.,Bolestova, G. I.
, p. 1333 - 1337 (2007/10/02)
The ionic hydrogenation, isomerization, and cyclization reactions of 3,7-dimethylenebicyclononane and related compounds have been studied.Ionic hydrogenation of the exocyclic methylene ?-bond occurs via the formation of alkyladamantanes.Reaction of 3,7-dimethylenebicyclononane with a chiral reagent results in the formation of an asymmetric adamantane derivative with an enantiomeric purity similar to that of the starting diene.
