37845-64-0

Upstream product

• 107-13-1 acrylonitrile 
• 21749-63-3 2-(methylamino)benzenethiol 

Downstream Products

• 81491-32-9 N-Methyl-2'-<(2-cyanomethyl)thio>-2α-<6-(benzyloxy)-3-methyl-3-hexenyl>-3.3-dimethylcyclobutane-1α-carboxanilide 
• 81521-01-9 N-Methyl-2'-<(2-cyanoethyl)thio>-2α-<(E)-6-(benzyloxy)-3-methyl-3-hexenyl>-3,3-dimethylcyclobutane-1β-carboxanilide 
• 136179-87-8 N-Methyl-2'-<(2-cyanoethyl)thio>-4-(5α-methanesulfonyloxymethyl-2,6,6-trimethyl-2-cyclohexen-1α-yl)butananilide 
• 141401-34-5 N-methyl-2'-<(2-cyanoethyl)thio>-<4-(3-p-toluenesulfonyloxy)propoxy>butananilide 
• 141401-33-4 N-methyl-2'-<(2-cyanoethyl)thio>-<5-(p-toluenesulfonyloxy)pentyloxy>acetanilide 
• 141401-36-7 N-methyl-2'-<(2-cyanoethyl)thio>-butananilide 
• 141401-35-6 N-methyl-2'-<(2-cyanoethyl)thio>-acetanilide 
• 123887-50-3 N-methyl-2'-<(2-cyanoethyl)thio>-3-<3α-(2-acetoxyethyl)-2,2,4α-trimethylcyclohexan-1α-yl>propionanilide 
• 123887-06-9 N-methyl-2'-<(2-cyanoethyl)thio>-3-<3α-(2-acetoxyethyl)-2,2,4-trimethyl-4-cyclohexen-1α-yl>propionanilide 
• 105631-09-2 N-methyl-2'-<(2-cyanoethyl)thio>-4-(5α-methanesulfonyloxymethyl-2,6,6-trimethyl-2-cyclohexen-1α-yl)-2-methylbutananilide 
• 1000069-73-7 N-{2-[(2-cyanoethyl)thio]phenyl}-N,1-dimethyl-1H-indole-2-carboxamide 
• 81491-36-3 N-Methyl-2'-<(2-cyanoethyl)thio>-2α-<(E)-6-<(methylsulfonyl)oxy>-3-methyl-3-hexenyl>-3,3-dimethylcyclobutane-1β-carboxanilide 
• 81521-07-5 N-Methyl-2'-<2-cyanoethyl)-thio>-2α-<(Z)-6-<(methyl-sulfonyl)oxy>-3-methyl-3-hexenyl>-3,3-dimethylcyclobutane-1α-carboxanilide 
• 81491-34-1 Acetic acid (E)-6-((1R,4S)-4-{[2-(2-cyano-ethylsulfanyl)-phenyl]-methyl-carbamoyl}-2,2-dimethyl-cyclobutyl)-4-methyl-hex-3-enyl ester 

Relevant academic research and scientific papers

Medium-Ring Ketone Synthesis. Total Syntheses of (+/-)-Isocaryophyllene and (+/-)-Caryophyllene

Total syntheses of (+/-)-isocaryophyllene and (+/-)-caryophyllene are reported.The key step involves a novel construction of the nine-membered ring in these natural products by a base-induced intramolecular acyl transfer reaction of 13-membered lactam sul