378753-76-5Relevant academic research and scientific papers
Synthesis and crystal structures of two new (Te, N,) type hybrid organotellurium ligands
Singh,Sooriyakumar,Kadarkaraisamy,Drake,Hursthouse,Light,Butcher
, p. 339 - 341 (2007/10/03)
The reaction of N-(2-chloroethyl)benzamide and N-[3-bromopropyl]phthalimide with ArTe- Na+ generated in situ by borohydride reduction of Ar2Te2, has resulted in N-[2-(4-methoxyphenyltelluro)ethyl] benzamide (L1) and N-[2-(4methoxyphenyl telluro)propyl] phthalimide (L2) respectively, which are potentially (Te, N)-type ligands. Their NMR (1H and 13C) spectra are characteristic and single crystal structures are solved. The Te-C(alkyl) distance [2.140(8)/2.151(4) A] is longer than Te-C(aryl) distance [2.107(8)/2.128(5) A].
