37902-41-3

Basic information

• Product Name: 2-Heptanone, 5-hydroxy-
• Synonyms: 2-Heptanone,5-hydroxy;5-hydroxy-heptan-2-one
• CAS NO: 37902-41-3
• Molecular Formula: C7H14O2
• Molecular Weight: 130.187
• Mol File: 37902-41-3.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 219.5±23.0 °C(Predicted)
• Density: 0.935±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 2-Heptanone, 5-hydroxy-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Heptanone, 5-hydroxy-(37902-41-3)
• EPA Substance Registry System: 2-Heptanone, 5-hydroxy-(37902-41-3)

Safety Data

• Hazardous Substances Data: 37902-41-3(Hazardous Substances Data)

Upstream product

• 110-43-0 n-pentyl methyl ketone 

Relevant articles and documents

Functionalization of non-activated C-H bonds in ketones and imines with HF/SbF5/CCl4

Reaction of cyclic ketones 2-6 and imines 15-17 in HF/SbF5 in presence of CCl4 yield hydroxy or fluoroderivatives, hydride abstraction occurring at a site located far from the functional group. Whereas ketones 2-5 yield only hydroxy derivatives, through cyclic carboxonium ion, imines 15, 16 N-protonated in the media conditions give only fluoroderivatives 18, 19, respectively, after quenching with HF-pyridine. Ring contraction is operative when starting from large membered ring ketones 24 and 25, and imine 26, leading to a mixture of hydroxy or fluoro cyclohexanones and/or cycloheptanones.