37903-87-0Relevant academic research and scientific papers
An efficient preparative route to substituted alkyl benzenesulfenates, versatile reagents for site-selective sulfenylative cyclizations
Harring, Scott R.,Livinghouse, Tom
, p. 893 - 902 (2007/10/03)
A versatile procedure for the synthesis of alkyl benzenesulfenates possessing varied patterns of nuclear substitution is described.
Antidiabetic furancarboxylic and thiphenecarboxylic acids
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, (2008/06/13)
Compounds of the structure STR1 wherein Z is oxygen or sulfur; R is (C1 -C2)alkoxy; phenoxy; benzyl; phenylthiomethyl; phenylthio; phenylthio monosubstituted in the 2-, 3- or 4-position with (C1 -C3)alkyl, pheny
CONCERNING THE MECHANISM OF THE FORMATION OF PHOSPHORANES FROM THE REACTION OF TRICOORDINATED PHOSPHORUS COMPOUNDS AND ALKYL BENZENESULFENATES
Denney, Donald B.,Denney, Dorothy Z.,Gavrilovic, Dragan M.
, p. 1 - 10 (2007/10/02)
Trimethyl phosphite has been allowed to react with methyl benzenesulfenate, methyl p-methoxybenzenesulfenate, methyl m-trifluoromethylbenzenesulfenate and methyl p-nitrobenzenesulfenate.The first three esters react at virtually the same rate whereas the p-nitro compound is considerably less reactive.These data support a mechanism which involves direct insertion of phosphorus into the S-O bond with some donation of lone pairs on sulfur into an orbital on phosphorus in the transition state.Other experiments show that the reaction is irreversible.A dithioaryltrioxyphosphorane has been shown to decompose to a phosphite and a diaryl disulfide.
Antidiabetic pyrrolecarboxylic acids
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, (2008/06/13)
Certain pyrrolecarboxylic and pyrroleacetic acid derivatives substituted on the pyrrole ring with thioether groups, acyl groups, phenyl, substituted phenyl, phenoxy, substituted phenoxy, benzyl or halo and optionally substituted on the pyrrole nitrogen with alkyl, and the pharmaceutically acceptable salts thereof, are useful in lowering the blood glucose levels of hyperglycemic animals.
