379269-55-3Relevant academic research and scientific papers
Formation of sp3-C1-bridged Cp/amido titanium and zirconium CpCN constrained-geometry Ziegler-Natta catalyst systems
Kunz, Klaus,Erker, Gerhard,D?ring, Steve,Bredeau, Stephane,Kehr, Gerald,Fr?hlich, Roland
, p. 1031 - 1041 (2008/10/08)
Formation of sp3-C1-bridged Cp/amido titanium and zirconium 'CpCN' constrained-geometry Ziegler-Natta catalyst systems was studied. The complexes were characterized by X-ray crystal structure analysis. Activation of the (CpCN)M(NR2)2 systems by treatment with a large excess of methylalumoxane in toluene solution gave homogeneous Ziegler-Natta catalysts for the polymerization of ethylene and the copolymerization of ethene with 1-octene.
