3796-00-7Relevant academic research and scientific papers
The reactivity of the cyclic systems (NPCl2)(3-n)(NSOX)n (n = 0, 1; X = Cl, Ph) towards aziridine
Huizen, A. A. van der,Jekel, A. P.,Rusch, J.,Grampel, J. C. van de
, p. 343 - 344 (2007/10/02)
The aziridinolysis of (NPCl2)3 and (NPCl2)2NSOCl proceeds both via a geminal and non-geminal pattern, whereas (NPCl2)2NSOPh reacts almost exclusively via a geminal pathway.The presence of a p-amino group (pyrrolidino, piperidino or morpholino) reduces the reactivity of the phosphorus centre concerned.
