38004-59-0

Basic information

• Product Name: 1,3,5-BENZENETRITHIOL
• Synonyms: 1,3,5-BENZENETRITHIOL;1,3,5-TRIMERCAPTOBENZENE;1,3,5-Benzenetristhiol;1,3,5-Benzenetrithiole
• CAS NO: 38004-59-0
• Molecular Formula: C₆H₆S₃
• Molecular Weight: 174.31
• Product Categories: Sulfur Compounds (for Synthesis);Synthetic Organic Chemistry
• Mol File: 38004-59-0.mol

Chemical Properties

• Melting Point: 60 °C
• Boiling Point: 327.6±22.0 °C(Predicted)
• Appearance: /
• Density: 1.369±0.06 g/cm3(Predicted)
• Storage Temp.: Refrigerator
• Solubility: soluble in Acetone
• PKA: 5.22±0.11(Predicted)
• CAS DataBase Reference: 1,3,5-BENZENETRITHIOL(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-BENZENETRITHIOL(38004-59-0)
• EPA Substance Registry System: 1,3,5-BENZENETRITHIOL(38004-59-0)

Safety Data

• Hazardous Substances Data: 38004-59-0(Hazardous Substances Data)

Usage

Uses

Used in Chemical Synthesis:
1,3,5-Benzenetrithiol is used as a building block in the synthesis of other organic compounds for its versatile chemical properties.
Used in Dye Production:
1,3,5-Benzenetrithiol is used as a precursor in the production of dyes, contributing to the development of various colorants for different applications.
Used in Pharmaceutical Industry:
1,3,5-Benzenetrithiol is used as an intermediate in the synthesis of pharmaceuticals, playing a crucial role in the development of new drugs.
Used in Agrochemicals:
1,3,5-Benzenetrithiol is used in the production of agrochemicals, aiding in the creation of effective pesticides and other agricultural chemicals.
Used in Electrochemical Studies:
1,3,5-Benzenetrithiol is utilized in electrochemical research for its unique properties, contributing to the advancement of electrochemistry.
Used in Odorants and Fragrances:
Due to its strong odor, 1,3,5-Benzenetrithiol is used in certain odorants and fragrances to provide distinctive scents.
Used in Polymer Production:
1,3,5-Benzenetrithiol is used in the production of polymers, leveraging its crosslinking abilities to enhance the properties of polymeric materials.
Used as a Corrosion Inhibitor:
1,3,5-Benzenetrithiol is used as a corrosion inhibitor for metal surfaces, protecting them from degradation and extending their lifespan.

InChI:InChI=1/C6H6S3/c7-4-1-5(8)3-6(9)2-4/h1-3,7-9H

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Relevant articles and documents

Discovery of practical production processes for arylsulfur pentafluorides and their higher homologues, bis- and tris(sulfur pentafluorides): Beginning of a new era of "super-trifluoromethyl" arene chemistry and its industry

Various arylsulfur pentafluorides, ArSF5, have long been desired in both academic and industrial areas, and ArSF5 compounds have attracted considerable interest in many areas such as medicines, agrochemicals, and other new materials, since the highly stable SF5 group is considered a "super-trifluoromethyl group" due to its significantly higher electronegativity and lipophilicity. This article describes the first practical method for the production of various arylsulfur pentafluorides and their higher homologues, bis- and tris(sulfur pentafluorides), from the corresponding diaryl disulfides or aryl thiols. The method consists of two steps: (Step 1) treatment of a diaryl disulfide or an aryl thiol with chlorine in the presence of an alkali metal fluoride, and (step 2) treatment of the resulting arylsulfur chlorotetrafluoride with a fluoride source, such as ZnF2, HF, and Sb(III/V) fluorides. The intermediate arylsulfur chlorotetrafluorides were isolated by distillation or recrystallization and characterized. The aspects of these new reactions are revealed and reaction mechanisms are discussed. As the method offers considerable improvement over previous methods in cost, yield, practicality, applicability, and large-scale production, the new processes described here can be employed as the first practical methods for the economical production of various arylsulfur pentafluorides and their higher homologues, which could then open up a new era of "super-trifluoromethyl" arene chemistry and its applications in many areas.

Syntheses d'analogues soufres d'isocannabinoides et de tetrahydrocannabinols

A systematic synthesis of thio compounds of isocannabinoids and tetrahydrocannabinols is described.The thiophenols were prepared by the Newman-Kwart reaction.The reaction of > has been used for the synthesis of citrylidene thiophenol.The structure of citrylidene monothioolivetol was established by spectroscopic and chemical methods.The synthesis of (-) 1'thio Δ1,6 THC is also described; this compound has potential biologic properties.